The interhalogen species iodine trichloride (IC13) may be synthesised according to the following reaction: 1₂ (s) + 3 Cl₂ (g) 2 IC13 (s) The thermodynamic data for the species are: S°(J mol¹) AH (kJ mol¹) 62.26 1₂ (g) 260.6 1₂ (s) 0 116.7 Ch₂ (g) 0 223.0 IC13 (s) -88.28 172.0 a) Calculate the Standard Gibbs Free Energy (4G) for the reaction at 25 °C. b) Is this reaction spontaneous at 25 °C? Explain your answer. c) At a given point as the reaction proceeds at 120 °C, the solution contains 0.52 g of I₂, 0.18 g of ICI, and 0.0824 mol L¹ of Cl₂. Calculate AG for the reaction under these conditions and determine in which direction the reaction will spontaneously proceed.
The interhalogen species iodine trichloride (IC13) may be synthesised according to the following reaction: 1₂ (s) + 3 Cl₂ (g) 2 IC13 (s) The thermodynamic data for the species are: S°(J mol¹) AH (kJ mol¹) 62.26 1₂ (g) 260.6 1₂ (s) 0 116.7 Ch₂ (g) 0 223.0 IC13 (s) -88.28 172.0 a) Calculate the Standard Gibbs Free Energy (4G) for the reaction at 25 °C. b) Is this reaction spontaneous at 25 °C? Explain your answer. c) At a given point as the reaction proceeds at 120 °C, the solution contains 0.52 g of I₂, 0.18 g of ICI, and 0.0824 mol L¹ of Cl₂. Calculate AG for the reaction under these conditions and determine in which direction the reaction will spontaneously proceed.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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