The highest kinetic energy electrons in the photoelectron spectrum of H2O using 21.22 eV radiation are at about 9 eV and show a large vibrational spacing of 0.41 eV. The symmetric stretching mode of the neutral H2O molecule lies at 3652 cm−1. (a) What conclusions can be drawn from the nature of the orbital from which the electron is ejected? (b) In the same spectrum of H2O, the band near 7.0 eV shows a long vibrational series with spacing 0.125 eV. The bending mode of H2O lies at 1596 cm−1. What conclusions can you draw about the characteristics of the orbital occupied by the photoelectron?
The highest kinetic energy electrons in the photoelectron spectrum of H2O using 21.22 eV radiation are at about 9 eV and show a large vibrational spacing of 0.41 eV. The symmetric stretching mode of the neutral H2O molecule lies at 3652 cm−1. (a) What conclusions can be drawn from the nature of the orbital from which the electron is ejected? (b) In the same spectrum of H2O, the band near 7.0 eV shows a long vibrational series with spacing 0.125 eV. The bending mode of H2O lies at 1596 cm−1. What conclusions can you draw about the characteristics of the orbital occupied by the photoelectron?
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The highest kinetic energy electrons in the photoelectron spectrum of H2O using 21.22 eV radiation are at about 9 eV and show a large vibrational spacing of 0.41 eV. The symmetric stretching mode of the neutral H2O molecule lies at 3652 cm−1. (a) What conclusions can be drawn from the nature of the orbital from which the electron is ejected? (b) In the same spectrum of H2O, the band near 7.0 eV shows a long vibrational series with spacing 0.125 eV. The bending mode of H2O lies at 1596 cm−1. What conclusions can you draw about the characteristics of the orbital occupied by the photoelectron?
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