H₂The Hamiltonian operator for○Â = + ²√√ ².——1 11+1 = + 1/201² ₁2 TA B R1in the Born-Oppenheimer approximation isTA B1 1+R8-1² +1 +1 1HTA B R1TA11 = -1/2 √²-HB+1R

We have to find Hamiltonian operator for H2+ in Born-oppenheimer approximation.

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The Hamiltonian operator for H₂ in the Born-Oppenheimer approximation is ....

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Techniques and applications of quantum theory

Quantum theory, often known as quantum physics, is the foundation of modern physics and encompasses the nature and behavior of matter and energy at the atomic and molecular levels. As the exact nature and behavior of atomic and subatomic particles are impossible to determine, the laws of classical physics do not apply to this discipline. As a result, quantum field theory is primarily based on assumptions and probabilities.

Question

H₂
The Hamiltonian operator for
○
Â = + ²√√ ².
——
1 11
+
1 = + 1/201² ₁
2 TA B R
1
in the Born-Oppenheimer approximation is
TA B
1 1
+
R
8-1² +1 +1 1
H
TA B R
1
TA
1
1 = -1/2 √²-
H
B
+
1
R

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