The Friedel-Crafts reaction of benzene with 2-chloro-3-methylbutane in the presence of AICI3 occurs with a carbocation rearrangement. Give mechanistic explanation and the product formed.
The Friedel-Crafts reaction of benzene with 2-chloro-3-methylbutane in the presence of AICI3 occurs with a carbocation rearrangement. Give mechanistic explanation and the product formed.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question

Transcribed Image Text:(a) The Friedel-Crafts reaction of benzene with 2-chloro-3-methylbutane in the presence of
AlCl3 occurs with a carbocation rearrangement. Give mechanistic explanation and the
product formed.
(b) Predict the product(s) will be formed from the following reactions:
(i) Bromination of p-methylbenzoic acid
(ii) Sulphonation of m-bromoanisole
(iii) Friedel-craft acylation of o-bromonitrobenzene
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