The following standard electrode potentials have been measured at a temperature of 298 K. Ag+ + e− → Ag E⁰= 0.80 V Ag2+ + e− → Ag+ E⁰= 1.98 V (i) Calculate the EMF for a cell in which the cell reaction is the disproportionation. 2Ag+ → Ag + Ag2+ (ii) Determine the Gibbs free energy for the disproportionation reaction. Comment on your result. (b) The EMF of the cell Ag(s) | Ag+ (saturated) | | Ag+(aq) (0.1M) | Ag is 0.417 V at 298 K. Calculate the solubility product of AgI.
The following standard electrode potentials have been measured at a temperature of 298 K. Ag+ + e− → Ag E⁰= 0.80 V Ag2+ + e− → Ag+ E⁰= 1.98 V (i) Calculate the EMF for a cell in which the cell reaction is the disproportionation. 2Ag+ → Ag + Ag2+ (ii) Determine the Gibbs free energy for the disproportionation reaction. Comment on your result. (b) The EMF of the cell Ag(s) | Ag+ (saturated) | | Ag+(aq) (0.1M) | Ag is 0.417 V at 298 K. Calculate the solubility product of AgI.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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(a) The following standard electrode potentials have been measured at a temperature of
298 K.
Ag+ + e− → Ag E⁰= 0.80 V
Ag2+ + e− → Ag+ E⁰= 1.98 V
(i) Calculate the EMF for a cell in which the cell reaction is the disproportionation.
2Ag+ → Ag + Ag2+
(ii) Determine the Gibbs free energy for the disproportionation reaction. Comment on your result.
(b) The EMF of the cell
Ag(s) | Ag+ (saturated) | | Ag+(aq) (0.1M) | Ag
is 0.417 V at 298 K. Calculate the solubility product of AgI.
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