The following sets of quantum numbers, listed in the order n, l, mų, and ms, were written for the last electrons added to an atom. Identify which sets are valid and classify the others by the rule or principle that is violated. Drag the appropriate items to their respective bins. > View Availahle Hint(s)

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Please answer question 1 part A and B

Part B
The following sets of quantum numbers, listed in the order n, l, me, and ms, were written for the last electrons added to an atom. Identify which sets are valid and classify the
others by the rule or principle that is violated.
Drag the appropriate items to their respective bins.
• View Available Hint(s)
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3 2 -2 +
3 1
-1 +
3 2 -1
3 1 -1 +
4 1 0 +:
0 +
2
3 1
1
3 2
3 1 0
2
2
4 1 0
-
2
3 1 +1 +
3 2
3 3 +1 +
2
3 2 +2 +
1
Pauli violation
Other violation
Valid
2.
|N -| N 1|
+ +
Transcribed Image Text:Part B The following sets of quantum numbers, listed in the order n, l, me, and ms, were written for the last electrons added to an atom. Identify which sets are valid and classify the others by the rule or principle that is violated. Drag the appropriate items to their respective bins. • View Available Hint(s) Reset Help 3 2 -2 + 3 1 -1 + 3 2 -1 3 1 -1 + 4 1 0 +: 0 + 2 3 1 1 3 2 3 1 0 2 2 4 1 0 - 2 3 1 +1 + 3 2 3 3 +1 + 2 3 2 +2 + 1 Pauli violation Other violation Valid 2. |N -| N 1| + +
When writing the ground-state electron configuration of a many-electron atom, three main rules must be followed:
• The aufbau principle: Electrons are added to the lowest energy orbitals available.
• The Pauli exclusion principle: No two electrons in an atom can have the same set of four quantum numbers (n, l, me, and ms).
• Hund's rule: For degenerate orbitals, the lowest energy state is attained when the number of electrons with the same spin is maximized. So for a degenerate set of
orbitals, one electron goes into each orbital until all the orbitals of the subshell are half-filled. Once all the orbitals of the subshell are half-filled the pairing of electrons
can take place.
Note that aufbau is the German word for "building up."
Part A
Classify each orbital diagram for ground-state electron configurations by the rule or principle it violates.
Drag the appropriate items to their respective bins.
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Reset
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|2P 1111 3 111 34 1||
4s 1
3d 1
3p 1 1 1
|4d 1|
2s 1
|4s 1
5s 1
|3s 1
Aufbau violation
Hund violation
Pauli violation
Transcribed Image Text:When writing the ground-state electron configuration of a many-electron atom, three main rules must be followed: • The aufbau principle: Electrons are added to the lowest energy orbitals available. • The Pauli exclusion principle: No two electrons in an atom can have the same set of four quantum numbers (n, l, me, and ms). • Hund's rule: For degenerate orbitals, the lowest energy state is attained when the number of electrons with the same spin is maximized. So for a degenerate set of orbitals, one electron goes into each orbital until all the orbitals of the subshell are half-filled. Once all the orbitals of the subshell are half-filled the pairing of electrons can take place. Note that aufbau is the German word for "building up." Part A Classify each orbital diagram for ground-state electron configurations by the rule or principle it violates. Drag the appropriate items to their respective bins. • View Available Hint(s) Reset Help |2P 1111 3 111 34 1|| 4s 1 3d 1 3p 1 1 1 |4d 1| 2s 1 |4s 1 5s 1 |3s 1 Aufbau violation Hund violation Pauli violation
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