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The following reduction potentials are measured at pH 14: CIO" + H¿O + 2 e¯ → Cl¯ + 2 OH¯ E° = 0.90 V ClO, + H¿O + 2 e¯ → ClO¯ + 2 OH¯ E° = 0.59 V (a) Will CIO¯ disproportionate spontaneously in basic solution? (b) Which is the stronger reducing agent at pH 14: CIO- or Cl-?

The following reduction potentials are measured at pH 14: CIO" + H¿O + 2 e¯ → Cl¯ + 2 OH¯ E° = 0.90 V ClO, + H¿O + 2 e¯ → ClO¯ + 2 OH¯ E° = 0.59 V (a) Will CIO¯ disproportionate spontaneously in basic solution? (b) Which is the stronger reducing agent at pH 14: CIO- or Cl-?

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The following reduction potentials are measured at pH 14: CIO" + H¿O + 2 e¯ → Cl¯ + 2 OH¯ E° = 0.90 V ClO, + H¿O + 2 e¯ → ClO¯ + 2 OH¯ E° = 0.59 V (a) Will CIO¯ disproportionate spontaneously in basic solution? (b) Which is the stronger reducing agent at pH 14: CIO- or Cl-?
Transcribed Image Text:The following reduction potentials are measured at pH 14: CIO" + H¿O + 2 e¯ → Cl¯ + 2 OH¯ E° = 0.90 V ClO, + H¿O + 2 e¯ → ClO¯ + 2 OH¯ E° = 0.59 V (a) Will CIO¯ disproportionate spontaneously in basic solution? (b) Which is the stronger reducing agent at pH 14: CIO- or Cl-?
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