The following reduction potentials are measured at pH 14: CIO" + H¿O + 2 e¯ → Cl¯ + 2 OH¯ E° = 0.90 V ClO, + H¿O + 2 e¯ → ClO¯ + 2 OH¯ E° = 0.59 V (a) Will CIO¯ disproportionate spontaneously in basic solution? (b) Which is the stronger reducing agent at pH 14: CIO- or Cl-?

The following reduction potentials are measured at pH 14: CIO" + H¿O + 2 e¯ → Cl¯ + 2 OH¯ E° = 0.90 V ClO, + H¿O + 2 e¯ → ClO¯ + 2 OH¯ E° = 0.59 V (a) Will CIO¯ disproportionate spontaneously in basic solution? (b) Which is the stronger reducing agent at pH 14: CIO- or Cl-?

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

The following reduction potentials are measured at pH 14:
CIO" + H¿O + 2 e¯ → Cl¯ + 2 OH¯
E° = 0.90 V
ClO, + H¿O + 2 e¯ → ClO¯ + 2 OH¯ E° = 0.59 V
(a) Will CIO¯ disproportionate spontaneously in basic
solution?
(b) Which is the stronger reducing agent at pH 14: CIO-
or Cl-?

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