the following reactions are discussed. Ts is the tolunesulfonyl group. CH; Tolunesulfonyl group (Ts) (a) OH OTs pyridine + C-Ts + HCI (S)-2-Octanol (S)-2-Octyl tosylate (b) OTS Sy2 ONa+ + + Na OTs ethanol Sodium acetate (S)-2-Octyl tosylate (R)-2-Octyl acetate In reaction (a), an S compound gives an S product. In reaction (b), an S compound gives an R product. Explain what is probably going on. (Hint: The oxygen atom in the starting material and product is the same in one reaction but not in the other.) What might this say about the second reaction?
the following reactions are discussed. Ts is the tolunesulfonyl group. CH; Tolunesulfonyl group (Ts) (a) OH OTs pyridine + C-Ts + HCI (S)-2-Octanol (S)-2-Octyl tosylate (b) OTS Sy2 ONa+ + + Na OTs ethanol Sodium acetate (S)-2-Octyl tosylate (R)-2-Octyl acetate In reaction (a), an S compound gives an S product. In reaction (b), an S compound gives an R product. Explain what is probably going on. (Hint: The oxygen atom in the starting material and product is the same in one reaction but not in the other.) What might this say about the second reaction?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:the following reactions are discussed. Ts is the tolunesulfonyl group.
CH;
Tolunesulfonyl group (Ts)
(a)
OH
OTs
pyridine
+ C-Ts
+ HCI
(S)-2-Octanol
(S)-2-Octyl tosylate
(b)
OTS
Sy2
ONa+ +
+ Na OTs
ethanol
Sodium acetate
(S)-2-Octyl tosylate
(R)-2-Octyl acetate
In reaction (a), an S compound gives an S product. In reaction (b), an S compound gives
an R product. Explain what is probably going on. (Hint: The oxygen atom in the starting
material and product is the same in one reaction but not in the other.) What might this
say about the second reaction?
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