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The following mechanism has been proposed for the reac- tion of nitric oxide and chlorine: Step 1. Step 2. NO(g) + Cl2(g) NOC2(g) NOCI2(g) + NO(g) →2 NOCI(g) -> (a) What is the overall reaction? (b) Identify any reaction intermediates. (c) What is the molecularity of each elementary step?

The following mechanism has been proposed for the reac- tion of nitric oxide and chlorine: Step 1. Step 2. NO(g) + Cl2(g) NOC2(g) NOCI2(g) + NO(g) →2 NOCI(g) -> (a) What is the overall reaction? (b) Identify any reaction intermediates. (c) What is the molecularity of each elementary step?

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Can you please answer these sub questions 12.77 and 12.78 and show all of the steps to the solution 

**12.77** The following mechanism has been proposed for the reaction of nitric oxide and chlorine: - **Step 1.** \( \text{NO} (g) + \text{Cl}_2 (g) \rightarrow \text{NOCl}_2 (g) \) - **Step 2.** \( \text{NOCl}_2 (g) + \text{NO} (g) \rightarrow 2 \text{NOCl} (g) \) (a) What is the overall reaction? (b) Identify any reaction intermediates. (c) What is the molecularity of each elementary step? **12.78** Give the molecularity and the rate law for each of the following elementary reactions: (a) \( \text{O}_3 (g) + \text{Cl} (g) \rightarrow \text{O}_2 (g) + \text{ClO} (g) \) (b) \( \text{NO}_2 (g) \rightarrow \text{NO} (g) + \text{O} (g) \) (c) \( \text{ClO} (g) + \text{O} (g) \rightarrow \text{Cl} (g) + \text{O}_2 (g) \) (d) \( \text{Cl}_2 (g) + \text{Cl} (g) + \text{N}_2 (g) \rightarrow \text{Cl}_2 (g) + \text{N}_2 (g) \) **12.79** Identify the molecularity and write the rate law for each of the following elementary reactions: (a) \( \text{I}_2 (g) \rightarrow 2 \text{I} (g) \) (b) \( 2 \text{NOBr} (g) + \text{Br}_2 (g) \rightarrow 2 \text{NOBr} (g) \) (c) \( \text{N}_2\text{O}_5 (g) \rightarrow \text{NO}_2 (g) + \text{NO}_3 (g) \) **12.80** The thermal decomposition of nitryl chloride, \( \text{NO}_2\text{Cl} \), is believed to occur by the following mechanism: 1. \( \text{NO}_2\text
Transcribed Image Text:**12.77** The following mechanism has been proposed for the reaction of nitric oxide and chlorine: - **Step 1.** \( \text{NO} (g) + \text{Cl}_2 (g) \rightarrow \text{NOCl}_2 (g) \) - **Step 2.** \( \text{NOCl}_2 (g) + \text{NO} (g) \rightarrow 2 \text{NOCl} (g) \) (a) What is the overall reaction? (b) Identify any reaction intermediates. (c) What is the molecularity of each elementary step? **12.78** Give the molecularity and the rate law for each of the following elementary reactions: (a) \( \text{O}_3 (g) + \text{Cl} (g) \rightarrow \text{O}_2 (g) + \text{ClO} (g) \) (b) \( \text{NO}_2 (g) \rightarrow \text{NO} (g) + \text{O} (g) \) (c) \( \text{ClO} (g) + \text{O} (g) \rightarrow \text{Cl} (g) + \text{O}_2 (g) \) (d) \( \text{Cl}_2 (g) + \text{Cl} (g) + \text{N}_2 (g) \rightarrow \text{Cl}_2 (g) + \text{N}_2 (g) \) **12.79** Identify the molecularity and write the rate law for each of the following elementary reactions: (a) \( \text{I}_2 (g) \rightarrow 2 \text{I} (g) \) (b) \( 2 \text{NOBr} (g) + \text{Br}_2 (g) \rightarrow 2 \text{NOBr} (g) \) (c) \( \text{N}_2\text{O}_5 (g) \rightarrow \text{NO}_2 (g) + \text{NO}_3 (g) \) **12.80** The thermal decomposition of nitryl chloride, \( \text{NO}_2\text{Cl} \), is believed to occur by the following mechanism: 1. \( \text{NO}_2\text
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