The following mechanism for the gas phase reaction of nitrogen dioxide with carbon monoxide at temperatures above 225 °C is consistent with the observed rate law. step 1: NO₂ + CO→→→→→→→ ONOCO step 2: (a) Identify the molecularity of each step in the mechanism. step 1 step 2 ONOCO →→→→NO + CO₂ + ♥ ✪ (b) Write the equation for the net reaction. Use the smallest integer coefficients possible. If a box is not needed, leave it blank. + (c) Identify any intemediates and/or catalysts in this mechanism. Catalyst: Enter formula. If none, leave box blank: Intermediate: Enter formula. If none, leave box blank:
The following mechanism for the gas phase reaction of nitrogen dioxide with carbon monoxide at temperatures above 225 °C is consistent with the observed rate law. step 1: NO₂ + CO→→→→→→→ ONOCO step 2: (a) Identify the molecularity of each step in the mechanism. step 1 step 2 ONOCO →→→→NO + CO₂ + ♥ ✪ (b) Write the equation for the net reaction. Use the smallest integer coefficients possible. If a box is not needed, leave it blank. + (c) Identify any intemediates and/or catalysts in this mechanism. Catalyst: Enter formula. If none, leave box blank: Intermediate: Enter formula. If none, leave box blank:
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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
Transcribed Image Text:The following mechanism for the gas phase reaction of nitrogen dioxide with carbon
monoxide at temperatures above 225 °C is consistent with the observed rate law.
step 1:
NO₂ + CO→→→→→→ONOCO
step 2:
4
(a) Identify the molecularity of each step in the mechanism.
step 1
step 2
ONOCO →→→→→NO + CO₂
+
♥
C
(b) Write the equation for the net reaction. Use the smallest integer coefficients possible.
If a box is not needed, leave it blank.
+
(c) Identify any intemediates and/or catalysts in this mechanism.
Catalyst: Enter formula. If none, leave box blank:
Intermediate: Enter formula. If none, leave box blank:

Transcribed Image Text:Identify each of the following elementary reactions as unimolecular, bimolecular, or
termolecular, and write the rate expression.
Reaction
(a) OH + HCI →→ H₂O + CI
(b) HO₂NO₂ - HO₂ + NO₂
(c)
HO + NO₂ + Ar →→ HNO3 +
Ar
Molecularity
◊
◊
◊
Rate expression
rate
rate =
rate =
Expert Solution

Step 1
Given ->
Step1-> NO2 + CO ----> ONOCO
Step2-> ONOCO -----> NO + CO2
-> Molecularity is the number of molecules that come together to reacts in an elementary reaction and it is equal to sum of stoichiometry coefficient of reactants in elementary reaction.
-> I a general equation aA + bB ----> product
Rate law expression is->
Rate = k[A]a[B]b
Step by step
Solved in 2 steps with 1 images

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