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The following gas phase reaction produces ethanol (C2H;OH) by catalytic hydrogenation of acetaldehyde (CH;CHO). The reaction reaches equilibrium at a temperature of T= T(N) T(N) (°C) and a pressure of 3 bar: 484 CH;CHO (g)+ H, (g)→ C,H,OH (g) The reactive system initially contains 1.5 moles of Hydrogen (H2) for each mole of acetaldehyde (CH3CHO). The mixture is assumed to be an ideal gas. T(N) is the temperature corresponding to the student number as shown in the attached Table 4.1 (a) At the equilibrium conditions of temperature and pressure: (i) Determine AG° (kJ/kmol) and AH° (kJ/kmol) of the reaction. (ii) Calculate the equilibrium constant at standard condition of temperature, K(298.15K). (iii) Assuming that the heat of reaction, AHº, does not change with temperature, calculate the equilibrium constant, K(Tn), at the temperature T(N).

The following gas phase reaction produces ethanol (C2H;OH) by catalytic hydrogenation of acetaldehyde (CH;CHO). The reaction reaches equilibrium at a temperature of T= T(N) T(N) (°C) and a pressure of 3 bar: 484 CH;CHO (g)+ H, (g)→ C,H,OH (g) The reactive system initially contains 1.5 moles of Hydrogen (H2) for each mole of acetaldehyde (CH3CHO). The mixture is assumed to be an ideal gas. T(N) is the temperature corresponding to the student number as shown in the attached Table 4.1 (a) At the equilibrium conditions of temperature and pressure: (i) Determine AG° (kJ/kmol) and AH° (kJ/kmol) of the reaction. (ii) Calculate the equilibrium constant at standard condition of temperature, K(298.15K). (iii) Assuming that the heat of reaction, AHº, does not change with temperature, calculate the equilibrium constant, K(Tn), at the temperature T(N).

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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The following gas phase reaction produces ethanol (C2H;OH) by catalytic hydrogenation of acetaldehyde (CH;CHO). The reaction reaches equilibrium at a temperature of T= T(N) T(N) (°C) and a pressure of 3 bar: 484 CH;CHO (g)+ H, (g)→ C,H,OH (g) The reactive system initially contains 1.5 moles of Hydrogen (H2) for each mole of acetaldehyde (CH3CHO). The mixture is assumed to be an ideal gas. T(N) is the temperature corresponding to the student number as shown in the attached Table 4.1 (a) At the equilibrium conditions of temperature and pressure: (i) Determine AG° (kJ/kmol) and AH° (kJ/kmol) of the reaction. (ii) Calculate the equilibrium constant at standard condition of temperature, K(298.15K). (iii) Assuming that the heat of reaction, AHº, does not change with temperature, calculate the equilibrium constant, K(Tn), at the temperature T(N).
Transcribed Image Text:The following gas phase reaction produces ethanol (C2H;OH) by catalytic hydrogenation of acetaldehyde (CH;CHO). The reaction reaches equilibrium at a temperature of T= T(N) T(N) (°C) and a pressure of 3 bar: 484 CH;CHO (g)+ H, (g)→ C,H,OH (g) The reactive system initially contains 1.5 moles of Hydrogen (H2) for each mole of acetaldehyde (CH3CHO). The mixture is assumed to be an ideal gas. T(N) is the temperature corresponding to the student number as shown in the attached Table 4.1 (a) At the equilibrium conditions of temperature and pressure: (i) Determine AG° (kJ/kmol) and AH° (kJ/kmol) of the reaction. (ii) Calculate the equilibrium constant at standard condition of temperature, K(298.15K). (iii) Assuming that the heat of reaction, AHº, does not change with temperature, calculate the equilibrium constant, K(Tn), at the temperature T(N).
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