The following data have been published for the second virial coefficient of methane (Thomas and van Steenwink, Nature, 187, 229, [1960]): T(K) B (cm³/mol) 108.45 -364.99 125.2 -267.97 149.1 -188.04 |186.4 -126.20 223.6 -82.62 249.3 -68.53 Calculate the residual enthalpy and entropy at 220 K. 20 bar assuming the validity of the truncated virial equation.

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
Question
The following data have been published for the second virial coefficient of methane (Thomas
and van Steenwink, Nature, 187, 229, [1960]):
T(K)
B (cm³/mol)
108.45
-364.99
125.2
-267.97
149.1
-188.04
|186.4
-126.20
223.6
-82.62
249.3
-68.53
Calculate the residual enthalpy and entropy at 220 K. 20 bar assuming the validity of the truncated
virial equation.
Transcribed Image Text:The following data have been published for the second virial coefficient of methane (Thomas and van Steenwink, Nature, 187, 229, [1960]): T(K) B (cm³/mol) 108.45 -364.99 125.2 -267.97 149.1 -188.04 |186.4 -126.20 223.6 -82.62 249.3 -68.53 Calculate the residual enthalpy and entropy at 220 K. 20 bar assuming the validity of the truncated virial equation.
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