The following data are for the gas phase decomposition of phosphine at 120 °C. PH3(g) →→→→1/4 P4(g) + 3/2 H₂(g) [PH3 ], M 2.64x10-2 time, s 0 1.32x10-2 6.60x10-3 3.30x10-3 26.7 53.4 Hint: It is not necessary to graph these data. (1) The half life observed for this reaction is (2) Based on these data, the rate constant for this S. 80.1 ✓order reaction is s-1.

Chemistry for Engineering Students
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Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.48PAE: 11.48 The following data were collected for the decomposition of NT),-: Time, f (min) [N2Os] (mol...
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The following data are for the gas phase decomposition of phosphine at 120 °C.
PH3(g) → 1/4 P4(g) + 3/2 H₂(g)
[PH3 ], M
time, s
2.64x10-2
0
1.32x10-2
26.7
Hint: It is not necessary to graph these data.
(1)
The half life observed for this reaction is |
(2)
Based on these data, the rate constant for this
6.60x10-3 3.30x10-3
53.4
80.1
S.
✓order reaction is
S-1.
Transcribed Image Text:The following data are for the gas phase decomposition of phosphine at 120 °C. PH3(g) → 1/4 P4(g) + 3/2 H₂(g) [PH3 ], M time, s 2.64x10-2 0 1.32x10-2 26.7 Hint: It is not necessary to graph these data. (1) The half life observed for this reaction is | (2) Based on these data, the rate constant for this 6.60x10-3 3.30x10-3 53.4 80.1 S. ✓order reaction is S-1.
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