The energy of the incoming photon, Eotal, is conserved in photoelectron spectroscopy. Therefore, the energy of the incoming photon is equal to the , plus the , so The energy of the incoming photon can also be expressed as , and the kinetic energy of the outgoing electron can be expressed as . The energy required to eject the electron corresponds to the . Substituting these expressions into the original expression for Ewtal produces the desired relationship between the speed of the ejected electron and the frequency of the incoming radiation,
The energy of the incoming photon, Eotal, is conserved in photoelectron spectroscopy. Therefore, the energy of the incoming photon is equal to the , plus the , so The energy of the incoming photon can also be expressed as , and the kinetic energy of the outgoing electron can be expressed as . The energy required to eject the electron corresponds to the . Substituting these expressions into the original expression for Ewtal produces the desired relationship between the speed of the ejected electron and the frequency of the incoming radiation,
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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