The endo rule in the Diels-Alder reaction predicts the formation of a bicyclic product. However, in many cases the endo compound is not the thermodynamic product. Briefly elaborate why this is the case.

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions
Section: Chapter Questions
Problem 20.35P: The following triene undergoes an intramolecular Diels-Alder reaction to give a bicyclic product....
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The endo rule in the Diels-Alder reaction predicts the formation of a bicyclic product. However, in many cases the endo compound is not the thermodynamic product. Briefly
elaborate why this is the case.
Transcribed Image Text:The endo rule in the Diels-Alder reaction predicts the formation of a bicyclic product. However, in many cases the endo compound is not the thermodynamic product. Briefly elaborate why this is the case.
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