The dissociation vapor pressure of a salt A2B(s) ⇌ A2(g) + B(g) at 367°C is 208 kPa but at 477°C it has risen to 547 kPa. For the dissociation reaction of A2B(s), calculate (i) the equilibrium constant, (ii) the standard reaction Gibbs energy, (iii) the standard enthalpy, and (iv) the standard entropy of dissociation, all at 422°C. Assume that the vapor behaves as a perfect gas and that ΔrH° and ΔrS° are independent of temperature in the range given.
The dissociation vapor pressure of a salt A2B(s) ⇌ A2(g) + B(g) at 367°C is 208 kPa but at 477°C it has risen to 547 kPa. For the dissociation reaction of A2B(s), calculate (i) the equilibrium constant, (ii) the standard reaction Gibbs energy, (iii) the standard enthalpy, and (iv) the standard entropy of dissociation, all at 422°C. Assume that the vapor behaves as a perfect gas and that ΔrH° and ΔrS° are independent of temperature in the range given.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The dissociation vapor pressure of a salt A2B(s) ⇌ A2(g) + B(g) at 367°C is 208 kPa but at 477°C it has risen to 547 kPa. For the dissociation reaction of A2B(s), calculate (i) the equilibrium constant, (ii) the standard reaction Gibbs energy, (iii) the standard enthalpy, and (iv) the standard entropy of dissociation, all at 422°C. Assume that the vapor behaves as a perfect gas and that ΔrH° and ΔrS° are independent of temperature in the range given.
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