The decomposition of hydrogen peroxide is catalyzed byiodide ion. The catalyzed reaction is thought to proceedby a two-step mechanism:H2O2(aq) + I - (aq)---->H2O(l) + IO- (aq) (slow)IO- (aq) + H2O2(aq)--->H2O(l) + O2(g) + I - (aq) (fast)(a) Write the chemical equation for the overall process.(b) Identify the intermediate, if any, in the mechanism.(c) Assuming that the first step of the mechanism is ratedetermining, predict the rate law for the overall process.
The decomposition of hydrogen peroxide is catalyzed byiodide ion. The catalyzed reaction is thought to proceedby a two-step mechanism:H2O2(aq) + I - (aq)---->H2O(l) + IO- (aq) (slow)IO- (aq) + H2O2(aq)--->H2O(l) + O2(g) + I - (aq) (fast)(a) Write the chemical equation for the overall process.(b) Identify the intermediate, if any, in the mechanism.(c) Assuming that the first step of the mechanism is ratedetermining, predict the rate law for the overall process.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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The decomposition of hydrogen peroxide is catalyzed by
iodide ion. The catalyzed reaction is thought to proceed
by a two-step mechanism:
H2O2(aq) + I - (aq)---->H2O(l) + IO- (aq) (slow)
IO- (aq) + H2O2(aq)--->H2O(l) + O2(g) + I - (aq) (fast)
(a) Write the chemical equation for the overall process.
(b) Identify the intermediate, if any, in the mechanism.
(c) Assuming that the first step of the mechanism is rate
determining, predict the rate law for the overall process.
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