The concentration of H2S in wastewater samples was determined by coulometric titration using Kl as mediator and I3 as "titrant". standard concentration Peak area (a.u) (ppm) 50 8354 100 16925 150 25218 200 33584 250 42002 A 50 mL wastewater sample was placed in a coulometric cell, added with excess KI and starch indicator. Electrolysis was carried out at a constant current of 84.6 mA for 386 s to reach the end point of the titration. What is the concentration of H2S in the sample (in ppm)?

The concentration of H2S in wastewater samples was determined by coulometric titration using Kl as mediator and I3 as "titrant". standard concentration Peak area (a.u) (ppm) 50 8354 100 16925 150 25218 200 33584 250 42002 A 50 mL wastewater sample was placed in a coulometric cell, added with excess KI and starch indicator. Electrolysis was carried out at a constant current of 84.6 mA for 386 s to reach the end point of the titration. What is the concentration of H2S in the sample (in ppm)?

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

+|| Σ D. For the cell shown, the measured cell potential, Ecell, is-0.3621 V at 25 °C. Pt(s) | H, (g, 0.853 atm) | H* (aq, ? M) || Cd²+(aq, 1.00 M) | Cd(s) The balanced reduction half-reactions for the cell, and their respective standard reduction potential values, E°, are 2H*(aq) + 2 e¯ – H, (g) A 00'0 = 07 24, Cd2+ (aq) + 2 e Cd(s) E° = -0.403 V %3D Calculate the Ht concentration. M. = [,H] 10:23 AM M. 11/9/2021 7734 F4 F5 F7 F8 F10 F11 F12 PrtScr Insert Delete Eゴ #3 Backspace 2$ ) 4. 5. 9. 7. R } 1 Enter F. K. H. Sh
How long would it take to electrodeposit all the Cu2+ in 0.200 L of 0.210 M CuSO4 solution with an applied potential difference of 0.255 V and a current of 3.10 amperes? Enter your answer in minutes.
A galvanic cell was constructed with a nickel electrode that was dipped into 1.1 M NiSO4 solution and a chromium electrode that was immersed into a solution containing Cr3+ at an unknown concentration. The potential of the cell was measured to be 0.557 V, with the chromium serving as the anode. The standard cell potential for this system was determined to be 0.487 V. What was the concentration of Cr3+ in the solution of unknown concentration?
Determine the cell potential (in volts) of a standard galvanic cell constructed using iron and lead metals and their associated solutions, 1M FeSO4 and 1M PbSO4.
For the cell shown, the measured cell potential, Ecell, is −0.3627 V at 25 °C. Pt(s) | H2(g,0.735 atm) | H+(aq,? M) || Cd2+(aq,1.00 M) | Cd(s) The balanced reduction half-reactions for the cell, and their respective standard reduction potential values, ?o, are 2H+(aq)+2e−⟶H2(g) ?o=0.00 V Cd2+(aq)+2e−⟶Cd(s) ?o=−0.403 V Calculate the H+ concentration in M.
Balance the following reactions. Calculate the cell potential and the Gibbs free energy of these reactions at standard conditions. Identify the reactions with K > 1 among the following redox reactions. Write the line representations for the Galvanic cells, indicating the anode and cathode.
Write the cell notation for an electrochemical cell consisting of an anode where Mg (s) is oxidized to Mg²+ (aq) and a cathode where Cr³+ (aq) is reduced to Cr²+ (aq) at a platinum electrode. Assume all aqueous solutions have a concentration of 1 mol/L. Mg(s)| Mg2+ (aq)|| Cr³+ (aq)| Cr²+ (aq)| Pt(s)
Balance the following reaction in basic solution. Ag(s) + Zn²+(aq) → Ag,O(ag) + Zn(s) Fill in the coefficients and substances for the balanced overall equation. Note: Do NOT leave any coeffient fields empty. If the coefficient is 1, choose "1" as opposed to leaving it blank. -- v Ag + -- v Zn2+ + v Zn + Ag,0 + -- v--