The compound oxygen difluoride is quite reactive, giving oxygen and HF when treated with water: OF₂(g) + H₂O(g) + O₂(g) + 2HF(g) AEºrxn = -318 kJ Using bond energies, calculate the bond dissociation energy of the O-F bond in OF2. Average Bond Energies (kJ/mol) Single Bonds H-H H-F H-CI 427 H-Br 363 H-1 295 432 565 C-H C-C C-N C-0 358 485 339 276 240 259 C-F C-CI C-Br C-1 C-S 413 347 305 *C=O(in CO₂) = 799 N-H N-N N-F N-CI N-Br N-O O-H 0-0 O-F O-CI 0-1 F-F F-CI F-Br CI-CI Cl-Br Br-Br O-F bond dissociation energy = 391 160 272 200 243 201 467 146 190 203 234 154 253 237 239 218 193 kJ/mol H I-cl 1-Br S-H S-F S-CI S-Br S-S Si-Si Si-H Si-C Si-O 149 208 175 347 327 253 218 266 340 393 360 452 Multiple Bonds C=C C=C 0 0 C=0* C=O N=O N=N N=N C=N CIN 614 839 495 745 1072 607 418 941 891 615

The compound oxygen difluoride is quite reactive, giving oxygen and HF when treated with water: OF₂(g) + H₂O(g) + O₂(g) + 2HF(g) AEºrxn = -318 kJ Using bond energies, calculate the bond dissociation energy of the O-F bond in OF2. Average Bond Energies (kJ/mol) Single Bonds H-H H-F H-CI 427 H-Br 363 H-1 295 432 565 C-H C-C C-N C-0 358 485 339 276 240 259 C-F C-CI C-Br C-1 C-S 413 347 305 C=O(in CO₂) = 799 N-H N-N N-F N-CI N-Br N-O O-H 0-0 O-F O-CI 0-1 F-F F-CI F-Br CI-CI Cl-Br Br-Br O-F bond dissociation energy = 391 160 272 200 243 201 467 146 190 203 234 154 253 237 239 218 193 kJ/mol H I-cl 1-Br S-H S-F S-CI S-Br S-S Si-Si Si-H Si-C Si-O 149 208 175 347 327 253 218 266 340 393 360 452 Multiple Bonds C=C C=C 0 0 C=0 C=O N=O N=N N=N C=N CIN 614 839 495 745 1072 607 418 941 891 615

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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