The compound oxygen difluoride is quite reactive, giving oxygen and HF when treated with water: OF₂(g) + H₂O(g) + O₂(g) + 2HF(g) AEºrxn = -318 kJ Using bond energies, calculate the bond dissociation energy of the O-F bond in OF2. Average Bond Energies (kJ/mol) Single Bonds H-H H-F H-CI 427 H-Br 363 H-1 295 432 565 C-H C-C C-N C-0 358 485 339 276 240 259 C-F C-CI C-Br C-1 C-S 413 347 305 *C=O(in CO₂) = 799 N-H N-N N-F N-CI N-Br N-O O-H 0-0 O-F O-CI 0-1 F-F F-CI F-Br CI-CI Cl-Br Br-Br O-F bond dissociation energy = 391 160 272 200 243 201 467 146 190 203 234 154 253 237 239 218 193 kJ/mol H I-cl 1-Br S-H S-F S-CI S-Br S-S Si-Si Si-H Si-C Si-O 149 208 175 347 327 253 218 266 340 393 360 452 Multiple Bonds C=C C=C 0 0 C=0* C=O N=O N=N N=N C=N CIN 614 839 495 745 1072 607 418 941 891 615

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### Compound Oxygen Difluoride Reaction and Bond Energy Calculation

The compound oxygen difluoride (OF₂) is quite reactive, giving oxygen and hydrogen fluoride (HF) when treated with water. The reaction is represented as:
\[ \text{OF}_2 (g) + \text{H}_2\text{O} (g) \rightarrow \text{O}_2 (g) + 2\text{HF} (g) \]
The standard enthalpy change of the reaction (ΔEºₓₙ) is -318 kJ.

**Objective:**
Using bond energies, calculate the bond dissociation energy of the O–F bond in OF₂.

#### Average Bond Energies (kJ/mol)

The table below provides average bond energies for various single and multiple bonds:

| Single Bonds  | Energy (kJ/mol) | Multiple Bonds | Energy (kJ/mol) |
|---------------|-----------------|----------------|-----------------|
| H–H           | 432             | C≡C            | 614             |
| H–F           | 565             | C=C            | 839             |
| H–Cl          | 427             | C≡O*           | 745             |
| H–Br          | 363             | C=O            | 1072            |
| H–I           | 298             | N=O            | 607             |
| C–H           | 413             | O=O            | 495             |
| C–C           | 347             | C=C            | 614             |
| C–N           | 305             | C=N            | 891             |
| C–O           | 358             | C≡N            | 615             |
| C–F           | 488             | N=N            | 418             |
| C–Cl          | 327             | N≡N            | 941             |
| C–Br          | 285             |                |                 |
| C–I           | 213             |                |                 |
| N–H           | 391             |                |                 |
| N–N           | 160             |                |                 |
| N–O           | 201             |                |                 |
| N–F           | 272             |                |                 |
| N–Cl          |
Transcribed Image Text:### Compound Oxygen Difluoride Reaction and Bond Energy Calculation The compound oxygen difluoride (OF₂) is quite reactive, giving oxygen and hydrogen fluoride (HF) when treated with water. The reaction is represented as: \[ \text{OF}_2 (g) + \text{H}_2\text{O} (g) \rightarrow \text{O}_2 (g) + 2\text{HF} (g) \] The standard enthalpy change of the reaction (ΔEºₓₙ) is -318 kJ. **Objective:** Using bond energies, calculate the bond dissociation energy of the O–F bond in OF₂. #### Average Bond Energies (kJ/mol) The table below provides average bond energies for various single and multiple bonds: | Single Bonds | Energy (kJ/mol) | Multiple Bonds | Energy (kJ/mol) | |---------------|-----------------|----------------|-----------------| | H–H | 432 | C≡C | 614 | | H–F | 565 | C=C | 839 | | H–Cl | 427 | C≡O* | 745 | | H–Br | 363 | C=O | 1072 | | H–I | 298 | N=O | 607 | | C–H | 413 | O=O | 495 | | C–C | 347 | C=C | 614 | | C–N | 305 | C=N | 891 | | C–O | 358 | C≡N | 615 | | C–F | 488 | N=N | 418 | | C–Cl | 327 | N≡N | 941 | | C–Br | 285 | | | | C–I | 213 | | | | N–H | 391 | | | | N–N | 160 | | | | N–O | 201 | | | | N–F | 272 | | | | N–Cl |
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