The complex (Fe(H,O)]* is paramagnetic. Is the H,0 ligand inducing a strong or weak field?

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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The complex (Fe(H,O)]* is paramagnetic. Is the H,0 ligand
inducing a strong or weak field?
Transcribed Image Text:The complex (Fe(H,O)]* is paramagnetic. Is the H,0 ligand inducing a strong or weak field?
Expert Solution
Step 1

The coordination complex is the compound that does not lose its identity in the solution. The coordination complex must have a central metal atom and ligand that are bonded together by a coordinate covalent bond. The complex is said to be paramagnetic if it has unpaired electrons in its orbitals while if it has paired electrons it is said to be diamagnetic. A strong field ligand helps in the pairing of electrons while the weak field lgand can not pair the electrons.

Step 2

To determine whether water molecule acts as a strong or weak field ligand.

The given complex is [Fe(H2O)6]2+ is paramagnetic in nature. The central atom Fe has the atomic number 26 and it's ground state electronic configuration is [Ar]3d64s2. In the given complex Fe has oxidation number +2 that means it loses two-electron from 4s orbitals. So, the electronic configuration of Fe2+ is [Ar]3d6. The filling of electrons in the octahedral complex of Fe2+ in the case of strong and weak field ligands. The electronic configuration in case of weak field ligand is t2g4eg2. The electronic configuration in the case of a strong field ligand is t2g6eg0.  Hence, the given complex is paramagnetic due to the presence of unpaired electrons in the case of a weak field ligand. Therefore, water is a weak field ligand.

Weak field ligand

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Strong filed ligand

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