The combined first and second law can be modified to take into account different forms of work present. Below we show an additional term to account for surface work in a single-component system: du TdS PdV + µdN + odA

The combined first and second law can be modified to take into account different forms of work present. Below we show an additional term to account for surface work in a single-component system: du TdS PdV + µdN + odA

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Problem 4:
a) The combined first and second law can be modified to take into account
different forms of work present. Below we show an additional term to
account for surface work in a single-component system:
dU
TdS
PdV + µdN + odA
Write the Gibbs-Duhem equation for this situation.
37

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