The cell Ag|AgCl(sat'd)||H+(a=x)glass electrode has a potential of -0.2094V when tne solution in the right hand compartment is a buffer of pH 4.006. The following potential are obtained when the buffer is replaced with unknowns:(a)-0.2806V and (b)-0.2132V. Calculate the pH and the hydrogen ion activity of each unknown.(c)Assuming an uncertainty of 0.001V in the junction potential,what is range of hydrogen ion activities within which the true value might be expected to lie?
The cell Ag|AgCl(sat'd)||H+(a=x)glass electrode has a potential of -0.2094V when tne solution in the right hand compartment is a buffer of pH 4.006. The following potential are obtained when the buffer is replaced with unknowns:(a)-0.2806V and (b)-0.2132V. Calculate the pH and the hydrogen ion activity of each unknown.(c)Assuming an uncertainty of 0.001V in the junction potential,what is range of hydrogen ion activities within which the true value might be expected to lie?
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Question
100%
The cell
Ag|AgCl(sat'd)||H+(a=x)glass electrode
has a potential of -0.2094V when tne solution in the right hand compartment is a buffer of pH 4.006. The following potential are obtained when the buffer is replaced with unknowns:(a)-0.2806V and (b)-0.2132V. Calculate the pH and the hydrogen ion activity of each unknown.(c)Assuming an uncertainty of 0.001V in the junction potential,what is range of hydrogen ion activities within which the true value might be expected to lie?
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 6 steps with 10 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY