The bond in H–CI can be explained by the overlap between an s orbital from hydrogen and a p orbital from chlorine, as shown in this diagram. (a) Draw the bonding and antibonding MOs that would result from such an interaction. (b) What is the symmetry of each of these MOs?

The bond in H–CI can be explained by the overlap between an s orbital from hydrogen and a p orbital from chlorine, as shown in this diagram. (a) Draw the bonding and antibonding MOs that would result from such an interaction. (b) What is the symmetry of each of these MOs?

Principles of Modern Chemistry

8th Edition

ISBN:9781305079113

Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler

Chapter6: Quantum Mechanics And Molecular Structure

Section: Chapter Questions

Problem 6P: Explain why 1g is the ground state for H2+ . By combining your answer with the answer to Problem 5,...

See similar textbooks

Related questions

Q: What happens if the if the symmetry properties of the orbitals do not match?

A: Symmetry provides additional quantum numbers. Atomic orbitals have the right symmetry atomic…

Q: electronic ure must be planar or nearly planar so that overlap of these port must be cyclic with…

A: Aromatic compounds are those which are cyclic, planar and have (4n + 2) pi electrons.

Q: 4. Explain what you understand when it comes to symmetry, symmetry element and point groups, giving…

A: Symmetry: Symmetry is characterized as a decent and proportionate similitude that is found in two…

Q: 2. What may be concluded about the nature of the irreducible representation corresponding each of…

A: Given : We have to tell nature of these mulliken symbol.

Q: Consider IF3O2 (with I as the central atom). How many isomers are possible (draw them)?Which is…

A: The isomers of IF3O2 are, The most stable isomer is figure (III). This is because, the adjacent…

Q: Draw the π-molecular orbitals for benzene, indicate the nodal planes and designate the proper energy…

A: Answer - The π-molecular orbitals for benzene -

Q: The MOE results and a discussion pertaining to the conformation of Thioflavin T at low potential…

A: Thioflavin T is a type of Biphenyl compound. In Biphenyl compounds, two phenyl groups are connected…

Q: Verify the point groups of the following molecule : F2

A: Point group basically depicts the 3D arrangement of a molecule using symmetry elements, such as axis…

Q: Which MOs are the HOMO and the LUMO in the excited state?

A: Molecular orbitals: When atomic orbitals of similar energy combine with each other then the…

Q: 2. Draw the structure of borazine and identify its symmetry elementals and operations

Q: How would you draw a molecular orbital diagram of butadiene showing the energies and occupancy ofthe…

Q: For monocyclic conjugated polyenes (such as cyclobutadiene and benzene) with each of N carbon atoms…

Q: Draw the distributioon oof a metal when it is in a octahedral field. determine the symmetry…

A: In the presence of octahedral field distribution of orbitals take place.

Q: Draw the MO diagram for the hypothetical square planar PtH42- ion. Consider only the s-interactions.…

Q: Which MOs are the HOMO and the LUMO in the excited state? for the MOs of 1,3,5-hexatriene:

Q: About the special type of hybridization involved in complexation (all are correct except Select one:…

A: In different type of hybridization, different type of structures of complexes or coordination…

Q: a. Cyclooctatetraene (COT) is shown below. Assume the molecule is planar, use the Hückel molecular…

A: Cyclooctatetraene is an eight membered cyclic hydrocarbon. The molecules which are planar and…

Q: (b) Using appropriate diagram(s), show which of the symmetry operation(s) does the [SO4]2- ion have:…

A: Symmetry elements are the topological operation in which exchange of the identical atoms takes place…

Q: Distinguish between pi (π) and delta (δ) bonding molecular orbital (MO) using the symmetry criteria.…

A: There are different types of bonding between atoms or groups in molecules. Molecular orbitals are…

Q: Sodium fluoride exists as a molecule in the gas phase under high tèmperature and vacuum conditions.…

A: We know that, Molecular formula of Sodium Fluoride is NaF Hence, For the MO Diagram for NaF, we need…

Q: Bro 1) The orbital potential energies for the 4s and 4p of Br are -18.65 ev and -12.49ev,…

Q: Which MOs are symmetric, and which are antisymmetric? for the MOs of 1,3,5-hexatriene:

A: Molecular orbitals can be represented by wave functions which relates the spatial arrangement of…

Q: Q1: give me concept terms for the following Briefly Germanium , forbidden gap , ev

A: The answer for first question is given below. Kindly repost the other questions as separate one. 1)…

Q: 1. Determine the highest order proper axis of rotation for each of the following geometric shapes.…

Q: Answer the following question for 1,3,5- hexatriene, the conjugated triene containing six carbons.…

A: The given compound is 1,3,5-hexatriene. To find: Which MOs are the frontier molecular orbitals

Q: Based on the shapes of p and d orbitals and the necessary match of symmetry, please predict and…

A: Atom A orbitals - p Atom B orbitals - d We have to draw the possible bonding interactions between A…

Q: Moleaular orbital (MO) theory relates to the symmetry properties & relative energies of atomic…

A: Molecular orbitals are formed when the atomic orbitals with nearly or equal energy are overlapped…

Q: Fine structure and hyperfine structure of atom with some example , in detail?

A: Fine structure and hyperfine structure of atom with some example , in detail?

Q: Which of the following depictions of a ligand group orbital would have the correct symmetry to form…

A: The Ligand Group Orbital with t2 bonding character that has the correct symmetry with a 2pz orbital…

Q: a) Draw the open structure of BH2ÇI. (At. No of B: 5) b) Predict the symmetry species of IR…

Q: Which of the following feature conjugation? D.

A: In chemistry, the term ''conjugation'' in the system can be defined as the system of connected…

Q: The C-C bond distance is agodd indicator of the degree of pi-backbonding.How?

A: In the inorganic chemistry, the phenomenon of pi backbonding occurs when electrons get transferred…

Q: (d). From the side: Down the axis: What is the symmetry designation for this orbital: o, ,0. , Tg ,…

Q: The molecule on the right belongs to А. С. В. С С. Си D. Cu point group. E. D B

A: D3V is the point group for the above given compound.

Q: 5) The following are actual calculated molecular orbitals for the diatomic molecule OF- (note the…

A: According to this theory valence electrons are occupied two types of orbitals such as bonding…

Q: (a) Complete the following table: Molecule/lon Geometry of molecule Key symmetry elements Point…

A: 1) B(F)(Cl)(Br) The given compound has 3 bond pairs and 0 lone pairs on the central atom. Thus it is…

Q: cyclobutadiene is very unsatble, why metal complex are stable? (use mo structure to explain)

A: Cyclobutadiene is very unstable hydrocarbon as it is anti-aromatic compound. It has four pi…

Q: Using appropriate diagram(s), show which of the symmetry operation(s) does the [SO4]2- ion have: (i)…

Q: Which one of the following is correct regarding the symmetry of molecular orbitals? O Tg is g O Od…

A: "g" and "u" Stands for the gerade and ungerade respectively. These are symmetry of molecular…

Q: Sketch the MO diagram for 1,3 budadiene. Identify the HOMO and LUMO along with all symmetric MO’s,…

A: MO diagrams: These diagram gives information regarding the linear combination of atomic orbitals and…

Q: (b) Using appropriate diagram(s), show which of the symmetry operation(s) does the [SO-]?" ion have:…

Q: Using symmetry, TOM and Orbital energy table Atomic, construct the OM Diagram for the following…

Q: Draw an energy diagram for the cyclopropenyl MOs. (The polygon rule is helpful.)Label each MO as…

A: Cyclopropenyl system is derived from cyclopropene consisting of a 3 membered cyclic ring with a…

Q: (a) Draw the orbital picture for :C=0: showing the explicit overlap of the contributing AOs. (b) How…

A: Molecular orbitals are formed by the Linear Combination of Atomic Orbitals (LCAO). Number of…

Q: The bond in Cl2 can be explained by the end-on overlap between two p AOs, as shown inthis diagram.…

A: The bond in Cl2 can be explained by the end-on overlap between two p AOs, as shown in this diagram.…

Question

The bond in H–CI can be explained by the overlap between an s orbital from hydrogen
and a p orbital from chlorine, as shown in this diagram. (a) Draw the bonding and
antibonding MOs that would result from such an interaction. (b) What is the symmetry
of each of these MOs?

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1

VIEW

Step 2

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 2 steps with 3 images

SEE SOLUTION Check out a sample Q&A here

Similar questions

For each of the following molecules, construct the MOs from the 2pz atomic orbitals perpendicular to the plane of the carbon atoms. (a) Cyclobutadiene HC (b) Allyl radical Indicate which, if any, of these orbitals have identical energies from symmetry considerations. Show the number of electrons occupying each MO in the ground state, and indicate whether either or both of the molecules are paramagnetic. Assume that the C atoms in the allyl radical are all sp2 hybridized.
The bond in Cl2 can be explained by the end-on overlap between two p AOs, as shown inthis diagram. (a) Draw the bonding and antibonding MOs that would result from such an interaction. (b) What is the symmetry of each of these MOs?
(a) Draw the orbital picture for :C=0: showing the explicit overlap of the contributing AOs. (b) How many MOs of T symmetry are there in total? (c) Draw the orbital energy diagram for CO and identify the HOMO and LUMO.
Draw the complete MO diagram for [CoCl6]4- Label the AOs and SALCs and MOs. Draw a sketch for each MO with the appropriate symmetry label
(c) An octahedral cluster molecule E6 in Oh point symmetry can be formed without a central atom and is bonded together using the six s and eighteen p orbitals on the six atoms. Each vertex comprises a sp hybrid orbital (radial) pointing into the cluster, and two p orbitals (tangential) at right angles to each other and to the centre of the cluster (see figure below). These are the same as the ligand orbitals used in o- and x-bonding in octahedral transition metal complexes. The bonding overlaps between these orbitals are shown below in A, B and C, and two of these are each part of a triply degenerate set and the other is singly degenerate - remember in O₂ symmetry x, y and z are degenerate. E E E E two tangential p orbitals B The reducible representation for these bonding orbitals is: radial sp orbital Oh E 8C 6C₂ 6C 3C₂ i 684 8S6 30h Ibonding 7 1 -1 1 -1 1 1 11 (i) Determine the three irreducible representations for the orbitals that contribute to cluster bonding to form the seven…
(a) Draw the molecular orbital diagram for hydrofluoric acid, HF. Be sure to clearly label orbital symmetry and indicate which orbitals are occupied by electrons.
Draw structures for the following showing correct geometry and identify all of the symmetry elements present ) ClO-.
For each of these contour representations of molecular orbitals,identify (a) the atomic orbitals (s or p) used to constructthe MO (b) the type of MO (s or p), (c) whether the MO isbonding or antibonding, and (d) the locations of nodalplanes.
6) Given below are the molecule BH3, its character table, and its molecular orbital diagram. By convention, the z-axis lies along the principal rotation axis: (a) What Mulliken symbol represents the symmetry of the MOs I-V? (b) Which of the given atomic orbitals on boron would match the MOS I-V? (c) Depict the in-phase (bonding) and out-of-phase (anti-bonding) of these MOS. B 2p orbitals B 2s orbitals II H 2s orbitals D₂ A, A₂' A," E" 1 1 2 1 1 2 2C, 3C₂ 0₂ 25, 1 1 1 1 1 -1 1 -1 1 -1 0 1 2 -1 -1 30, 1 1 -1 R₂ -1 0 -1 -1 -1 1 1 0 (x, y) (R., R.) x+y²,2² (x²-y, xy) (xz, yz)
5. Draw the complete MO diagram for BF3. What is the point group? Label the AOs and SALCs and MOS. Draw a sketch for each MO with the appropriate symmetry label. What is the overall bond order? Which orbitals represent the lone pairs? What is the ionization energy in units of eV for BF3?
Which one of the following is correct regarding the symmetry of molecular orbitals? O Ta is g O Od is g O O, is u O Os is u O n, is u
The orbital potential energies for the 4s and 4p of Br are -18.65 ev and -12.49 ev, respectively. Recall that the H 1s is -13.61 ev. The MO diagrams for HBr is not exactly the same as HF. Draw the MO diagram for HBr, including energy levels, each orbitals shape, each orbitals character (meaning what atomic orbitals contribute to each M.O. and how much), symmetry labels indicate the HOMO and LUMO, the bond order (show your work), whether the molecule is paramagnetic or diamagnetic. Compare and contrast the MO diagrams of HF and HBr.