The bond force constant for the Cul (copper iodide) is 174 Nm ¹. (a) Calculate the approximate wavelength of the light absorbed due to the transition v=0→2 in Cul. (b) Estimate the isotopic shift (fractional change in wavelength) for the same transition between Cul and Cul. (c) The fraction of molecules with vibration energy level j at temperature T is given by pie (1-e) where y=hw/kBT. Calculate the temperature of a gas in which 1/2 the Cul molecules are in the vibrational ground state. (d) In general, diatomic molecules such as HCl and CO are mostly in the vibrational ground state at room temperature. Give two reasons why this is not the case for Cul.
The bond force constant for the Cul (copper iodide) is 174 Nm ¹. (a) Calculate the approximate wavelength of the light absorbed due to the transition v=0→2 in Cul. (b) Estimate the isotopic shift (fractional change in wavelength) for the same transition between Cul and Cul. (c) The fraction of molecules with vibration energy level j at temperature T is given by pie (1-e) where y=hw/kBT. Calculate the temperature of a gas in which 1/2 the Cul molecules are in the vibrational ground state. (d) In general, diatomic molecules such as HCl and CO are mostly in the vibrational ground state at room temperature. Give two reasons why this is not the case for Cul.
College Physics
11th Edition
ISBN:9781305952300
Author:Raymond A. Serway, Chris Vuille
Publisher:Raymond A. Serway, Chris Vuille
Chapter1: Units, Trigonometry. And Vectors
Section: Chapter Questions
Problem 1CQ: Estimate the order of magnitude of the length, in meters, of each of the following; (a) a mouse, (b)...
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Please help with part d)
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