The blood alcohol C2H5OH level can be determined by titrating a sample of blood plasma with an acidic potassium dichromate solution, resulting in the production of Cr3+ (aq) and carbon dioxide. The reaction can be monitored because the dichromate ion (Cr2O72-) is orange in solution, and the Cr3+ ion is green. The unbalanced redox equation is: Cr2O72-(aq) + C2H5OH(aq) --> Cr3+(aq) +CO2(g) If 17.11 mL of 0.0806 M  potassium dichromate solution is required to titrate 15.9 g of blood plasma, determine the mass percent of alcohol in the blood.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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The blood alcohol C2H5OH level can be determined by titrating a sample of blood plasma with an acidic potassium dichromate solution, resulting in the production of Cr3+ (aq) and carbon dioxide. The reaction can be monitored because the dichromate ion (Cr2O72-) is orange in solution, and the Cr3+ ion is green. The unbalanced redox equation is:

Cr2O72-(aq) + C2H5OH(aq) --> Cr3+(aq) +CO2(g)

If 17.11 mL of 0.0806 M  potassium dichromate solution is required to titrate 15.9 g of blood plasma, determine the mass percent of alcohol in the blood.

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