The addition of NO accelerates the decomposition ofN2O, possibly by the following mechanism:NO(g) + N2O(g)--->N2(g) + NO2(g)2 NO2(g)--->2 NO(g) + O2(g)(a) What is the chemical equation for the overall reaction?Show how the two steps can be added to give theoverall equation. (b) Is NO serving as a catalyst or an intermediatein this reaction? (c) If experiments show thatduring the decomposition of N2O, NO2 does not accumulatein measurable quantities, does this rule out the proposedmechanism?

The addition of NO accelerates the decomposition ofN2O, possibly by the following mechanism:NO(g) + N2O(g)--->N2(g) + NO2(g)2 NO2(g)--->2 NO(g) + O2(g)(a) What is the chemical equation for the overall reaction?Show how the two steps can be added to give theoverall equation. (b) Is NO serving as a catalyst or an intermediatein this reaction? (c) If experiments show thatduring the decomposition of N2O, NO2 does not accumulatein measurable quantities, does this rule out the proposedmechanism?

Organic Chemistry

8th Edition

ISBN:9781305580350

Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote

Chapter4: Acids And Bases

Section: Chapter Questions

Problem 4.20P

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Question

The addition of NO accelerates the decomposition of
N₂O, possibly by the following mechanism:
NO(g) + N₂O(g)--->N₂(g) + NO₂(g)
2 NO₂(g)--->2 NO(g) + O₂(g)
(a) What is the chemical equation for the overall reaction?
Show how the two steps can be added to give the
overall equation. (b) Is NO serving as a catalyst or an intermediate
in this reaction? (c) If experiments show that
during the decomposition of N₂O, NO₂ does not accumulate
in measurable quantities, does this rule out the proposed
mechanism?

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