Tarnish on silver is the compound Ag2O. A tarnished silver spoon is placed in an aluminum pan of boiling water. When enough salt is added so that the solution conducts electricity, the tarnish disappears. Imagine that the two halves of this redox reaction were separated and connected with a wire and a salt bridge. Part A Calculate the standard cell potential given the following standard reduction potentials: Al+ +3e Al; E =-1.66 V Agt +eAg; E =0.799 V Express your answer to two decimal places and include the appropriate units. > View Available Hint(s) Eo cell Value Units

Tarnish on silver is the compound Ag2O. A tarnished silver spoon is placed in an aluminum pan of boiling water. When enough salt is added so that the solution conducts electricity, the tarnish disappears. Imagine that the two halves of this redox reaction were separated and connected with a wire and a salt bridge. Part A Calculate the standard cell potential given the following standard reduction potentials: Al+ +3e Al; E =-1.66 V Agt +eAg; E =0.799 V Express your answer to two decimal places and include the appropriate units. > View Available Hint(s) Eo cell Value Units

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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A certain half-reaction has a standard reduction potential -0 red = = +0.90 V. An engineer proposes using this half-reaction at the cathode of a galvanic cell that must provide at least 0.70 V of electrical power. The cell will operate under standard conditions. Note for advanced students: assume the engineer requires this half-reaction to happen at the cathode of the cell. ロ→ロ 0 Is there a minimum standard reduction potential that the half-reaction used at the anode of this cell can have? yes, there is a minimum. ☐v red If so, check the "yes" box and calculate the minimum. Round your answer to 2 decimal places. If there is no lower limit, check the "no" box. no minimum Ś ? 0 Is there a maximum standard reduction potential that the half-reaction used at the anode of this cell can have? yes, there is a maximum. Ov red If so, check the "yes" box and calculate the maximum. Round your answer to 2 decimal places. If there is no upper limit, check the "no" box. no maximum E E = = X
Use the standard reduction potentials given below to predict if a reaction will occur between Ag(s) and F2 (g), when the two are brought in contact via standard half-cells in a voltaic cell. F2 (g)+2e7 →2F (aq) E red Agt (ag)+e → Ag(s) E red + = If a reaction will occur, write a balanced net ionic equation for the reaction, assuming that the product ions are in aqueous solution. If no reaction will occur, leave all boxes blank. (Use the lowest possible coefficients. Be sure to specify states such as (aq) or (s). If a box is not needed, leave it blank.) - 2.870 V 0.799 V +
A galvanic cell is powered by the following redox reaction: 2+ + 3 Cu²+ (aq) + Cr(OH)3(s) + 5OH¯(aq) → 3 Cut (aq) + Cro (aq) + 4H₂O(1) Answer the following questions about this cell. If you need any electrochemical data, be sure you get it from the ALEKS Data tab. Write a balanced equation for the half-reaction that takes place at the cathode. Write a balanced equation for the half-reaction that takes place at the anode. Calculate the cell voltage under standard conditions. Round your answer to 2 decimal places. 0 0 0 E = v V ロ→ロ X 5
A galvanic (voltaic) cell consists of an electrode composed of aluminum in a 1.0 M aluminum ion solution and another electrode composed of gold in a 1.0 M gold(III) ion solution, connected by a salt bridge. Calculate the standard potential for this cell at 25 °C. Refer to the list of standard reduction potentials. Excell V
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Consider the reaction below:2 Ag(aq) + +Fe(s) → 2 Ag(s) + Fe^2+(aq) ΔG° = −241.0kJmol a. Calculate the equilibrium constant for this reaction.b. Calculate the standard cell potential for this reaction.
4
Using standard reduction potentials from the ALEKS Data tab, calculate the standard reaction free energy following redox reaction. Be sure your answer has the correct number of significant digits. ■ 10Fe²+ (aq) +2103 (aq) +12H* (aq) → 10Fe³ KJ 10Fe³+ (aq) + ¹₂ (s) + 6H₂O (1) x10 X Ś AGO for the ? olo 18 Ar
an irregularly shaped metal part was made from a particular alloy was galvanized with zinc using a Zn(NO3)2 solution. When a current of 1.95 A was used, it took exactly 1.7 hours to deposit a 0.0267-mm layer of zinc on the part. What was the total surface area of the part? The density of zinc is 7.410 g/cm^3. Assume the efficiency is 100%. Calculate your answer to at least 2 decimal places.
5. Consider the following under acidic conditions: Cu(s) + MnO4¹ (aq) → Mn²+ + Cu²+ i ii Write the balanced half-reaction for the oxidation that occurs. Write the balanced half-reaction for the reduction that occurs. iii Write the balanced redox reaction. iv Write the potential for each half-reaction next to it (the values are in your text) V Calculate the cell potential. vi Calculate AG at 25 °C. vii Is this reaction spontaneous? Why? viii Draw and label the cell for this reaction. ix Write the line notation for the cell.
Use standard reduction potentials to calculate the standard free energy change in kJ for the reaction: (aq) + 2Cu+ (aq) → Pb(s) + 2Cu²+ (aq) AG° Pb²+ = Pb²+ (aq) + 2e¯ → Pb(s) Ee = -0.126 V red 2+ Cu²+ (aq) + e → Cu+ (aq) Fº red kJ K for this reaction would be = = 0.153 V + than one.
Silver can be electroplated at the cathode of an electrolysis cell according to the following half-reaction: Ag^+(aq)+e^-→Ag(s) What mass of silver plates onto the cathode when a current of 7.9 A flows through the cell for 73 min ?