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Table 6-1 Free Energies of Hydrolysis of Common Phosphate-Containing CHAPTER 6 Biochemical Energy Production 277 Metabolic Compounds Type Free Energy enol phosphates Example of Hydrolysis (kcal/mole) phosphoenolpyruvate. -14.8 0~P-O Н Н acyl phosphates 1,3-bisphosphoglycerate acetyl phosphate -11.8 -11.3 0~P-O R guanidine phosphates creatine phosphate arginine phosphate -10.3 N-H O -9.1 R-N-C-N~P-O Н НоО triphosphates -7.7 ATP AMP + PP, * ATP ADP + P* -7.5 R-O-P-0~P-0~P-0 -7.8 PP; 2P, ADP AMP + P, diphosphates -7.5 R-O-P-0~P-O -5.0 glucose 1-phosphate fructose 6-phosphate AMP glucose 6-phosphate glycerol 3-phosphate -3.8 sugar phosphates -3.4 adenosine + P 3.3 -2.2 R-O-P-O *The notation P; is used as a general designation for any free monophosphate species present in cellular fluid. Free diphosphate ions are designated as PP; ("i" stands for inorganic). R.

Table 6-1 Free Energies of Hydrolysis of Common Phosphate-Containing CHAPTER 6 Biochemical Energy Production 277 Metabolic Compounds Type Free Energy enol phosphates Example of Hydrolysis (kcal/mole) phosphoenolpyruvate. -14.8 0~P-O Н Н acyl phosphates 1,3-bisphosphoglycerate acetyl phosphate -11.8 -11.3 0~P-O R guanidine phosphates creatine phosphate arginine phosphate -10.3 N-H O -9.1 R-N-C-N~P-O Н НоО triphosphates -7.7 ATP AMP + PP, * ATP ADP + P* -7.5 R-O-P-0~P-0~P-0 -7.8 PP; 2P, ADP AMP + P, diphosphates -7.5 R-O-P-0~P-O -5.0 glucose 1-phosphate fructose 6-phosphate AMP glucose 6-phosphate glycerol 3-phosphate -3.8 sugar phosphates -3.4 adenosine + P 3.3 -2.2 R-O-P-O *The notation P; is used as a general designation for any free monophosphate species present in cellular fluid. Free diphosphate ions are designated as PP; ("i" stands for inorganic). R.

Chemistry
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Which compound in each of the following pairs of phosphate-containing compounds releases more free energy upon hydrolysis?

a. ATP and Phosphoenolpyruvate

b. Creatine phosphate and ADP

c. Glucose 1-phosphate and 1,3-biphosphoglycerate

d. AMP and glycerol 3-phosphate

 

 

Table 6-1 Free Energies of Hydrolysis of Common Phosphate-Containing CHAPTER 6 Biochemical Energy Production 277 Metabolic Compounds Type Free Energy enol phosphates Example of Hydrolysis (kcal/mole) phosphoenolpyruvate. -14.8 0~P-O Н Н acyl phosphates 1,3-bisphosphoglycerate acetyl phosphate -11.8 -11.3 0~P-O R guanidine phosphates creatine phosphate arginine phosphate -10.3 N-H O -9.1 R-N-C-N~P-O Н НоО triphosphates -7.7 ATP AMP + PP, * ATP ADP + P* -7.5 R-O-P-0~P-0~P-0 -7.8 PP; 2P, ADP AMP + P, diphosphates -7.5 R-O-P-0~P-O -5.0 glucose 1-phosphate fructose 6-phosphate AMP glucose 6-phosphate glycerol 3-phosphate -3.8 sugar phosphates -3.4 adenosine + P 3.3 -2.2 R-O-P-O *The notation P; is used as a general designation for any free monophosphate species present in cellular fluid. Free diphosphate ions are designated as PP; ("i" stands for inorganic). R.
Transcribed Image Text:Table 6-1 Free Energies of Hydrolysis of Common Phosphate-Containing CHAPTER 6 Biochemical Energy Production 277 Metabolic Compounds Type Free Energy enol phosphates Example of Hydrolysis (kcal/mole) phosphoenolpyruvate. -14.8 0~P-O Н Н acyl phosphates 1,3-bisphosphoglycerate acetyl phosphate -11.8 -11.3 0~P-O R guanidine phosphates creatine phosphate arginine phosphate -10.3 N-H O -9.1 R-N-C-N~P-O Н НоО triphosphates -7.7 ATP AMP + PP, * ATP ADP + P* -7.5 R-O-P-0~P-0~P-0 -7.8 PP; 2P, ADP AMP + P, diphosphates -7.5 R-O-P-0~P-O -5.0 glucose 1-phosphate fructose 6-phosphate AMP glucose 6-phosphate glycerol 3-phosphate -3.8 sugar phosphates -3.4 adenosine + P 3.3 -2.2 R-O-P-O *The notation P; is used as a general designation for any free monophosphate species present in cellular fluid. Free diphosphate ions are designated as PP; ("i" stands for inorganic). R.
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