Table 6-1 Free Energies of Hydrolysis of Common Phosphate-Containing CHAPTER 6 Biochemical Energy Production 277 Metabolic Compounds Type Free Energy enol phosphates Example of Hydrolysis (kcal/mole) phosphoenolpyruvate. -14.8 0~P-O Н Н acyl phosphates 1,3-bisphosphoglycerate acetyl phosphate -11.8 -11.3 0~P-O R guanidine phosphates creatine phosphate arginine phosphate -10.3 N-H O -9.1 R-N-C-N~P-O Н НоО triphosphates -7.7 ATP AMP + PP, * ATP ADP + P* -7.5 R-O-P-0~P-0~P-0 -7.8 PP; 2P, ADP AMP + P, diphosphates -7.5 R-O-P-0~P-O -5.0 glucose 1-phosphate fructose 6-phosphate AMP glucose 6-phosphate glycerol 3-phosphate -3.8 sugar phosphates -3.4 adenosine + P 3.3 -2.2 R-O-P-O *The notation P; is used as a general designation for any free monophosphate species present in cellular fluid. Free diphosphate ions are designated as PP; ("i" stands for inorganic). R.
Table 6-1 Free Energies of Hydrolysis of Common Phosphate-Containing CHAPTER 6 Biochemical Energy Production 277 Metabolic Compounds Type Free Energy enol phosphates Example of Hydrolysis (kcal/mole) phosphoenolpyruvate. -14.8 0~P-O Н Н acyl phosphates 1,3-bisphosphoglycerate acetyl phosphate -11.8 -11.3 0~P-O R guanidine phosphates creatine phosphate arginine phosphate -10.3 N-H O -9.1 R-N-C-N~P-O Н НоО triphosphates -7.7 ATP AMP + PP, * ATP ADP + P* -7.5 R-O-P-0~P-0~P-0 -7.8 PP; 2P, ADP AMP + P, diphosphates -7.5 R-O-P-0~P-O -5.0 glucose 1-phosphate fructose 6-phosphate AMP glucose 6-phosphate glycerol 3-phosphate -3.8 sugar phosphates -3.4 adenosine + P 3.3 -2.2 R-O-P-O *The notation P; is used as a general designation for any free monophosphate species present in cellular fluid. Free diphosphate ions are designated as PP; ("i" stands for inorganic). R.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
Related questions
Concept explainers
Organic Chemistry of Metabolic Pathways
Metabolic pathways allude to the arrangement of chemical catalyzed reactions that lead to the transformation of a substance into the final product. Metabolic pathways incorporate a progression of reaction where the substrate is changed continuously and the transitional metabolites are persistently recovered.
Glucogenesis
Glucogenesis is a metabolic pathway in which glucose is produced from carbon substrates that are not carbohydrates. This process is observed in plants, animals, fungi, bacteria and other micro organisms. The general definition for glucogenesis or gluconeogenesis is as follows,
Question
100%
Which compound in each of the following pairs of phosphate-containing compounds releases more free energy upon hydrolysis?
a. ATP and Phosphoenolpyruvate
b. Creatine phosphate and ADP
c. Glucose 1-phosphate and 1,3-biphosphoglycerate
d. AMP and glycerol 3-phosphate
Transcribed Image Text:Table 6-1 Free Energies of Hydrolysis of Common Phosphate-Containing
CHAPTER 6 Biochemical Energy Production 277
Metabolic Compounds
Type
Free Energy
enol phosphates
Example
of Hydrolysis
(kcal/mole)
phosphoenolpyruvate.
-14.8
0~P-O
Н
Н
acyl phosphates
1,3-bisphosphoglycerate
acetyl phosphate
-11.8
-11.3
0~P-O
R
guanidine phosphates
creatine phosphate
arginine phosphate
-10.3
N-H O
-9.1
R-N-C-N~P-O
Н
НоО
triphosphates
-7.7
ATP AMP + PP, *
ATP ADP + P*
-7.5
R-O-P-0~P-0~P-0
-7.8
PP; 2P,
ADP AMP + P,
diphosphates
-7.5
R-O-P-0~P-O
-5.0
glucose 1-phosphate
fructose 6-phosphate
AMP
glucose 6-phosphate
glycerol 3-phosphate
-3.8
sugar phosphates
-3.4
adenosine + P
3.3
-2.2
R-O-P-O
*The notation P; is used as a general designation for any free monophosphate species present in cellular
fluid. Free diphosphate ions are designated as PP; ("i" stands for inorganic).
R.
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
This is a popular solution!
Trending now
This is a popular solution!
Step by step
Solved in 4 steps
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.Recommended textbooks for you
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY