TABLE 13.4 Measured and Expected van't Hoff Factors for Several Substances at 25 °C Concentration Compound 0.100 m 0.0100 m 0.00100 m Expected Value Sucrose 1.00 1.00 1.00 1.00 NaCI 1.87 1.94 1.97 2.00 K2SO4 2.32 2.70 2.84 3.00 MgSO4 1.21 1.53 1.82 2.00

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Chapter1: Chemical Foundations
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Calculate the freezing point of a 0.100 m aqueous solution
of K2SO4, (a) ignoring interionic attractions, and (b) taking
interionic attractions into consideration by using the
van’t Hoff factor (Table 13.4).

TABLE 13.4 Measured and Expected van't Hoff
Factors for Several Substances at 25 °C
Concentration
Compound
0.100 m
0.0100 m 0.00100 m Expected Value
Sucrose
1.00
1.00
1.00
1.00
NaCI
1.87
1.94
1.97
2.00
K2SO4
2.32
2.70
2.84
3.00
MgSO4
1.21
1.53
1.82
2.00
Transcribed Image Text:TABLE 13.4 Measured and Expected van't Hoff Factors for Several Substances at 25 °C Concentration Compound 0.100 m 0.0100 m 0.00100 m Expected Value Sucrose 1.00 1.00 1.00 1.00 NaCI 1.87 1.94 1.97 2.00 K2SO4 2.32 2.70 2.84 3.00 MgSO4 1.21 1.53 1.82 2.00
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