Answered: In P = k1 + k2/(k3 + T)+ k4T + ks In T…

Introduction to Chemical Engineering Thermodynamics

8th Edition

ISBN:9781259696527

Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart

Chapter1: Introduction

Section: Chapter Questions

Problem 1.1P

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Question

Nitrogen at 760 torr and 300^oC containing 10 mol% anthraquinone
(A) is cooled to 200^oC. Calculate the % desublimation of A.Vapor pressure data for solid A are as follows:

These data can be fitted to the Antoine equation (2-39) using the first three constants.

In P = k1 + k2/(k3 + T)+ k4T + ks In T + k6T (2-39)

T, °C:
Vapor pressure, torr.
190.0
234.2
264.3
285.0
10
40
100

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