Suppose the formation of nitryl fluoride proceeds by the following mechanism: rate constant step 1 elementary reaction NO₂ (g)+F₂ (g) → NO₂F (g) +F (g) - k₁ F (g) + NO₂ (g) → NO₂F (g) k₂ Suppose also k₁ «k₂. That is, the first step is much slower than the second. 2 Write the balanced chemical equation for the overall chemical reaction. Write the experimentally- observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates. rate = k ローロ 00 X

Chemistry for Engineering Students
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Author:Lawrence S. Brown, Tom Holme
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Chapter11: Chemical Kinetics
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Problem 11.104PAE
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Suppose the formation of nitryl fluoride proceeds by the following mechanism:
step
elementary reaction
1 NO₂ (g) +F₂ (g) → NO₂F (g) +F (g)
k₁
2
F (g) + NO₂ (g) → NO₂F (g)
k₂
Suppose also k₁ « k₂. That is, the first step is much slower than the second.
Write the balanced chemical
equation for the overall
chemical reaction.
Write the experimentally-
observable rate law for the
overall chemical reaction.
Note: your answer should not
contain the concentrations of
any intermediates.
rate = k
rate constant
ロ→ロ
0|0
X
Transcribed Image Text:Suppose the formation of nitryl fluoride proceeds by the following mechanism: step elementary reaction 1 NO₂ (g) +F₂ (g) → NO₂F (g) +F (g) k₁ 2 F (g) + NO₂ (g) → NO₂F (g) k₂ Suppose also k₁ « k₂. That is, the first step is much slower than the second. Write the balanced chemical equation for the overall chemical reaction. Write the experimentally- observable rate law for the overall chemical reaction. Note: your answer should not contain the concentrations of any intermediates. rate = k rate constant ロ→ロ 0|0 X
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