Sucrose is a chiral compound and enantio-pure sucrose has specific rotation [?]D20 = +66.5°. A sample of synthesized sucrose from the organic chemistry lab was tested, and the specific rotation of the sample is [?]D20= +60.1°. a) determine the enantiomeric excess (ee) of the sample. b) calculate the ratio of two enantiomers c) draw the structure of the minor enantiomer in the sample.

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Sucrose is a chiral compound and enantio-pure sucrose has specific rotation [?]D20 = +66.5°. A sample of synthesized sucrose from the organic chemistry lab was tested, and the specific rotation of the sample is [?]D20= +60.1°.

a) determine the enantiomeric excess (ee) of the sample.

b) calculate the ratio of two enantiomers

c) draw the structure of the minor enantiomer in the sample.

 

### Structure of (+)-Sucrose

The image above depicts the chemical structure of the disaccharide sugar molecule known as (+)-sucrose. Sucrose is composed of two monosaccharides: glucose and fructose.

#### Detailed Description:

1. **Glucose Unit**:
   - The glucose part of sucrose is shown on the left side.
   - It has a six-membered ring structure, known as a pyranose form.
   - The hydroxyl groups (OH) are attached to specific carbon atoms, and the CH₂OH group is located at the top, indicating the orientation of the glucose unit.

2. **Fructose Unit**:
   - The fructose component is depicted on the right side.
   - It has a five-membered ring structure, known as a furanose form.
   - Similar to glucose, it contains hydroxyl groups (OH) attached to various carbon atoms, with a CH₂OH moiety positioned at the three o'clock position.

3. **Glycosidic Bond**:
   - The glucose and fructose units are connected by an oxygen atom bridging their respective rings.
   - This bond is specifically a glycosidic linkage, formed between the anomeric carbon of the glucose and the carbon of the fructose, signifying a condensation reaction.

Understanding this structure is essential for appreciating how sucrose functions biologically and why it is widely used as a sweetener.
Transcribed Image Text:### Structure of (+)-Sucrose The image above depicts the chemical structure of the disaccharide sugar molecule known as (+)-sucrose. Sucrose is composed of two monosaccharides: glucose and fructose. #### Detailed Description: 1. **Glucose Unit**: - The glucose part of sucrose is shown on the left side. - It has a six-membered ring structure, known as a pyranose form. - The hydroxyl groups (OH) are attached to specific carbon atoms, and the CH₂OH group is located at the top, indicating the orientation of the glucose unit. 2. **Fructose Unit**: - The fructose component is depicted on the right side. - It has a five-membered ring structure, known as a furanose form. - Similar to glucose, it contains hydroxyl groups (OH) attached to various carbon atoms, with a CH₂OH moiety positioned at the three o'clock position. 3. **Glycosidic Bond**: - The glucose and fructose units are connected by an oxygen atom bridging their respective rings. - This bond is specifically a glycosidic linkage, formed between the anomeric carbon of the glucose and the carbon of the fructose, signifying a condensation reaction. Understanding this structure is essential for appreciating how sucrose functions biologically and why it is widely used as a sweetener.
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