Substituents on an aromatic ring can have several effects on electrophilic aromatic substitution reactions. Substituents can activate or deactivate the ring to substitution, donate or withdraw electrons inductively, donate or withdraw electrons through resonance, and direct substitution either to the ortho/para or to the meta positions. From the lists of substituents, select the substituents that correspond to each indicated property. The substituents are written as -XY, where X is the atom directly bound to the aromatic ring. These substituents activate the ring towards substitution. These substituents withdraw electrons through resonance. O -OCOCH, O -OH O -CI O -COOH O -NH, O -CH3 O -So;H O -CN These substituents give ortho/para-directed substitution. O -F O -NHCOCH, O -COOH O -NO,
Substituents on an aromatic ring can have several effects on electrophilic aromatic substitution reactions. Substituents can activate or deactivate the ring to substitution, donate or withdraw electrons inductively, donate or withdraw electrons through resonance, and direct substitution either to the ortho/para or to the meta positions. From the lists of substituents, select the substituents that correspond to each indicated property. The substituents are written as -XY, where X is the atom directly bound to the aromatic ring. These substituents activate the ring towards substitution. These substituents withdraw electrons through resonance. O -OCOCH, O -OH O -CI O -COOH O -NH, O -CH3 O -So;H O -CN These substituents give ortho/para-directed substitution. O -F O -NHCOCH, O -COOH O -NO,
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Reactions of Ethers
Ethers (R-O-R’) are compounds formed by replacing hydrogen atoms of an alcohol (R-OH compound) or a phenol (C6H5OH) by an aryl/ acyl group (functional group after removing single hydrogen from an aromatic ring). In this section, reaction, preparation and behavior of ethers are discussed in the context of organic chemistry.
Epoxides
Epoxides are a special class of cyclic ethers which are an important functional group in organic chemistry and generate reactive centers due to their unusual high reactivity. Due to their high reactivity, epoxides are considered to be toxic and mutagenic.
Williamson Ether Synthesis
An organic reaction in which an organohalide and a deprotonated alcohol forms ether is known as Williamson ether synthesis. Alexander Williamson developed the Williamson ether synthesis in 1850. The formation of ether in this synthesis is an SN2 reaction.
Question
Transcribed Image Text:Substituents on an aromatic ring can have several effects on electrophilic aromatic substitution reactions. Substituents can
activate or deactivate the ring to substitution, donate or withdraw electrons inductively, donate or withdraw electrons
through resonance, and direct substitution either to the ortho/para or to the meta positions. From the lists of substituents,
select the substituents that correspond to each indicated property. The substituents are written as -XY, where X is the
atom directly bound to the aromatic ring.
These substituents activate the ring towards substitution.
These substituents withdraw electrons
through resonance.
O -OCOCH;
O -OH
-CI
O -COOH
O -NH,
O -CH,
O -so,H
O -CN
These substituents give ortho/para-directed substitution.
I -F
O -NHCOCH,
O -COOH
O -NO,
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