Question 4Calculate the frequency factor (A).Studies have shown that the reaction occurs viathe following mechanism.kiCl2O4k-1Step 1:2 Cl02(fast equilibrium)k2Step 2:C2O4 + OH-→ ClO;¯+HCIO2(slow)k3Step 3:HCIO2 + OH → ClO2¯+H2O(fast)Question 5: Identify the intermediate/s and therate-determining step.ki2 ClO2 2 C2O4k-1Step 1:(fast equilibrium)k2→ ClO3¯+HC1O2Step 2:C204 + OH-(slow)k3Step 3:HC1O2 + OH-ClO2- + H2O(fast)Question 6Is the proposed mechanism consistent with theexperimentally determined rate law? Show yoursolution to justify your answer.ki2 ClO2 2 C2O4k-1Step 1:(fast equilibrium)k2Step 2:C204 + OH-→ ClO3¯+ HCIO2(slow)k3Step 3:HCIO2 + OH-→ ClO2-+ H2O(fast)Question 7Draw the transition state for Step 3. Identify thebond/s forming/breaking.

Since you have asked multiple questions, we will solve the first one (Question no. 5) for you. For…

Studies have shown that the reaction occurs via the following mechanism. ki 2 ClO2 2 Cl2O4 k-1 k2 Step 1: (fast equilibrium) Step 2: C204 + OH- → CIO3¯+ HC1O2 (slow) k3 Step 3: HC1O2 + OH → ClO2¯+ H2O (fast) Question 5: Identify the intermediate/s and the rate-determining step.

Studies have shown that the reaction occurs via the following mechanism. ki 2 ClO2 2 Cl2O4 k-1 k2 Step 1: (fast equilibrium) Step 2: C204 + OH- → CIO3¯+ HC1O2 (slow) k3 Step 3: HC1O2 + OH → ClO2¯+ H2O (fast) Question 5: Identify the intermediate/s and the rate-determining step.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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