STUDENT NAME N I CO/45 Nieves D. Real World Examples Example 1 In a lab a chemist needs to identify which metal cation is in an unknown toxic waste 3+ sample. On a piece of chromatography paper he spots solutions of Cu?*, Ni² and Fe" and his unknown. He uses a developing solution of a mixture of HCI, water and 2+ acetone. What are the Rf values for each cation sample? Rf Distance traveled Show calc. Solvent front 14.5 cm distance Cu²+ 5.5 cm :2+ 11.8 cm Fe * 8.0 cm Unknown 11.1 cm What is the likely identity of the unknown? Briefly explain your answer. Example 2 chemist is running a forensic laboratory. Using the Rf values in the table below, ermine which solvent she would use to analyze a sample seized by the police in a g smuggling case. Explain your answer. Drug Cocaine Methamphetamine Acetone/water Water/denatured alcohol Vinegar/acetone 0.11 0.14 0.42 0.71 0.76 0.45 Morphine *Note: though the example is reasonable, the data is concocted. 0.72 0.82 0.75

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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STUDENT NAME N I CO/45 Nieves
D. Real World Examples
Example 1
In a lab a chemist needs to identify which metal cation is in an unknown toxic waste
3+
sample. On a piece of chromatography paper he spots solutions of Cu?*, Ni² and Fe"
and his unknown. He uses a developing solution of a mixture of HCI, water and
2+
acetone.
What are the Rf values for each cation sample?
Rf
Distance traveled
Show calc.
Solvent front
14.5 cm
distance
Cu²+
5.5 cm
:2+
11.8 cm
Fe *
8.0 cm
Unknown
11.1 cm
What is the likely identity of the unknown? Briefly explain your answer.
Example 2
chemist is running a forensic laboratory. Using the Rf values in the table below,
ermine which solvent she would use to analyze a sample seized by the police in a
g smuggling case. Explain your answer.
Drug
Cocaine
Methamphetamine
Acetone/water Water/denatured alcohol Vinegar/acetone
0.11
0.14
0.42
0.71
0.76
0.45
Morphine
*Note: though the example is reasonable, the data is concocted.
0.72
0.82
0.75
Transcribed Image Text:STUDENT NAME N I CO/45 Nieves D. Real World Examples Example 1 In a lab a chemist needs to identify which metal cation is in an unknown toxic waste 3+ sample. On a piece of chromatography paper he spots solutions of Cu?*, Ni² and Fe" and his unknown. He uses a developing solution of a mixture of HCI, water and 2+ acetone. What are the Rf values for each cation sample? Rf Distance traveled Show calc. Solvent front 14.5 cm distance Cu²+ 5.5 cm :2+ 11.8 cm Fe * 8.0 cm Unknown 11.1 cm What is the likely identity of the unknown? Briefly explain your answer. Example 2 chemist is running a forensic laboratory. Using the Rf values in the table below, ermine which solvent she would use to analyze a sample seized by the police in a g smuggling case. Explain your answer. Drug Cocaine Methamphetamine Acetone/water Water/denatured alcohol Vinegar/acetone 0.11 0.14 0.42 0.71 0.76 0.45 Morphine *Note: though the example is reasonable, the data is concocted. 0.72 0.82 0.75
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