Step 4. Separation of and testing for Hg,2* and Ag*. To the solid from step 2, add 2 mL of 6 M NH,OH. Agitate and centrifuge. A gray to black solid indicates the presence of Hg22* in the original solution. Decant the liquid (if solid was present). Add concentrated HNO3 dropwise until blue litmus paper turns red. A white precipitate indicates the presence of Ag*.

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Group I Cations A
1. Explain why litmus paper is used in step 4. Why is blue litmus paper used rather than red
litmus paper?
Transcribed Image Text:Group I Cations A 1. Explain why litmus paper is used in step 4. Why is blue litmus paper used rather than red litmus paper?
Group I Cations
of 6 M HCI; centrifuge for ~1 minute. Decant the solution and add an additional one or two drops
of 6 M HCI; if no additional precipitate forms, the precipitation is complete. If it was incomplete,
centrifuge to obtain the additional solid; then decant the liquid, add 1 or 2 drops of 6 M HCI, and
repeat the procedure until no precipitate forms. Discard the supernatant into the appropriate
waste container or keep for later experiments if your instructor so indicates.
Add 1.5 mL of cold deionized or distilled water to the precipitate to wash; agitate, centrifuge,
and discard the water to the appropriate waste container. Repeat the wash procedure. The
solid contains Pb2*, Ag*, and/or Hg22*.
Step 2. Separation of Pb2*.
Add 1 mL of boiling water to the solid from step 1. Agitate, centrifuge, and decant the liquid.
Repeat the extraction, combining the supernatant. The liquid should contain Pb?* if any is present.
Step 3. Testing for Pb2*.
Add 2 or 3 drops of 0.2 M K2CRO4 solution to the combined supernatant from step 2. Formation
of a yellow solid (PbCrO4) indicates the presence of Pb2*.
Step 4. Separation of and testing for Hg,2* and Ag*.
To the solid from step 2, add 2 mL of 6 M NH,OH. Agitate and centrifuge. A gray to black solid
indicates the presence of Hg2* in the original solution.
Decant the liquid (if solid was present). Add concentrated HNO3 dropwise until blue litmus paper
turns red. A white precipitate indicates the presence of Ag*.
Transcribed Image Text:Group I Cations of 6 M HCI; centrifuge for ~1 minute. Decant the solution and add an additional one or two drops of 6 M HCI; if no additional precipitate forms, the precipitation is complete. If it was incomplete, centrifuge to obtain the additional solid; then decant the liquid, add 1 or 2 drops of 6 M HCI, and repeat the procedure until no precipitate forms. Discard the supernatant into the appropriate waste container or keep for later experiments if your instructor so indicates. Add 1.5 mL of cold deionized or distilled water to the precipitate to wash; agitate, centrifuge, and discard the water to the appropriate waste container. Repeat the wash procedure. The solid contains Pb2*, Ag*, and/or Hg22*. Step 2. Separation of Pb2*. Add 1 mL of boiling water to the solid from step 1. Agitate, centrifuge, and decant the liquid. Repeat the extraction, combining the supernatant. The liquid should contain Pb?* if any is present. Step 3. Testing for Pb2*. Add 2 or 3 drops of 0.2 M K2CRO4 solution to the combined supernatant from step 2. Formation of a yellow solid (PbCrO4) indicates the presence of Pb2*. Step 4. Separation of and testing for Hg,2* and Ag*. To the solid from step 2, add 2 mL of 6 M NH,OH. Agitate and centrifuge. A gray to black solid indicates the presence of Hg2* in the original solution. Decant the liquid (if solid was present). Add concentrated HNO3 dropwise until blue litmus paper turns red. A white precipitate indicates the presence of Ag*.
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