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Specify the reagent you would use in each step of the following synthesis: a. LIAIH4 b. H₂SO4 c. HCI d. HBr e. SOCI2 H step 1 step 2 Reagents Available CI f. PBr3 k. CH3CH₂MgBr g. Dess-Martin periodinane (DMP) 1. C6H5MgBr h. NaH i. NaOH j. CH3MgBr (phenylmagnesium bromide) m. (CH3)2CHMgBr n. CrO3 Write the letters of the reagents in the boxes below. Reagent for step 1 Reagent for step 2

Specify the reagent you would use in each step of the following synthesis: a. LIAIH4 b. H₂SO4 c. HCI d. HBr e. SOCI2 H step 1 step 2 Reagents Available CI f. PBr3 k. CH3CH₂MgBr g. Dess-Martin periodinane (DMP) 1. C6H5MgBr h. NaH i. NaOH j. CH3MgBr (phenylmagnesium bromide) m. (CH3)2CHMgBr n. CrO3 Write the letters of the reagents in the boxes below. Reagent for step 1 Reagent for step 2

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Organic Chemistry Synthesis Problem** In this problem, you are asked to specify the reagent used in each step of a given synthesis reaction. The starting compound is: - A molecule with the structure CH3-CO-CH3 (acetone). The target product is: - CH3-CH2-CH2-Cl (n-propyl chloride). The synthesis pathway involves 2 steps: 1. Step 1: A reagent that will convert the starting material into an intermediate. 2. Step 2: A reagent that will convert the intermediate into the final product. **Reagents Available:** a. LiAlH4 b. H2SO4 c. HCl d. HBr e. SOCl2 f. PBr3 g. Dess-Martin periodinane (DMP) h. NaH i. NaOH j. CH3MgBr k. CH3CH2MgBr l. C6H5MgBr (phenylmagnesium bromide) m. (CH3)2CHMgBr n. CrO3 **Instructions:** Select reagents from the list to perform the specified conversions. 1. **Reagent for Step 1**: - **First**: Reduction of the carbonyl group to convert the acetone (CH3-CO-CH3) into 2-propanol (CH3-CHOH-CH3). - The appropriate reagent from the list: LiAlH4 (Option a). 2. **Reagent for Step 2**: - **Second**: Convert the alcohol group into a chloro derivative to get the final product (CH3-CH2-CH2-Cl). - The appropriate reagent from the list: SOCl2 (Option e). Therefore, - The reagent for step 1 is **a (LiAlH4)**. - The reagent for step 2 is **e (SOCl2)**. **Answer:** - **Reagent for step 1:** a - **Reagent for step 2:** e
Transcribed Image Text:**Organic Chemistry Synthesis Problem** In this problem, you are asked to specify the reagent used in each step of a given synthesis reaction. The starting compound is: - A molecule with the structure CH3-CO-CH3 (acetone). The target product is: - CH3-CH2-CH2-Cl (n-propyl chloride). The synthesis pathway involves 2 steps: 1. Step 1: A reagent that will convert the starting material into an intermediate. 2. Step 2: A reagent that will convert the intermediate into the final product. **Reagents Available:** a. LiAlH4 b. H2SO4 c. HCl d. HBr e. SOCl2 f. PBr3 g. Dess-Martin periodinane (DMP) h. NaH i. NaOH j. CH3MgBr k. CH3CH2MgBr l. C6H5MgBr (phenylmagnesium bromide) m. (CH3)2CHMgBr n. CrO3 **Instructions:** Select reagents from the list to perform the specified conversions. 1. **Reagent for Step 1**: - **First**: Reduction of the carbonyl group to convert the acetone (CH3-CO-CH3) into 2-propanol (CH3-CHOH-CH3). - The appropriate reagent from the list: LiAlH4 (Option a). 2. **Reagent for Step 2**: - **Second**: Convert the alcohol group into a chloro derivative to get the final product (CH3-CH2-CH2-Cl). - The appropriate reagent from the list: SOCl2 (Option e). Therefore, - The reagent for step 1 is **a (LiAlH4)**. - The reagent for step 2 is **e (SOCl2)**. **Answer:** - **Reagent for step 1:** a - **Reagent for step 2:** e
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