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Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Transcribed Image Text:The heat capacity is the the heat flow divided by the temperature change. If the process is carried out quasi-statically (i.e. reversibly), we
can use the thermodynamic definition of entropy:
dq = TdS
Sarev
T
Cp = → ds =
CP= TOS
ras
Take the pressure derivative:
8
OP CP = To as
ар ат
Which Maxwell relation will allow you to complete the proof with only one more step?
° (#), = (#),
=
P
° - (), = (*),
P
° (#). --(#),
O
=
(OS) T
° (#), = (#),
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