Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
Shown below is the EI mass spectrum of ethyl cyclobutane carboxylate. Without drawing any structures or mechanisms, determine which fragment comes about from a Mclarfetty rearrangement. What jumped out at you? And once you have identifed the fragment ion that comes from the Mclarfetty rearrangement, provide the strcture of the fragment and a clear mechanism for its formation.
![Shown below is the El masS spectrum of ethyl cyclobutane carboxylate.
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Transcribed Image Text:Shown below is the El masS spectrum of ethyl cyclobutane carboxylate.
55
100
80
60
40
83
100
20
128
m/z
30
40
50
60
70
80
90
100
110
120
130
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