Shown below is the El masS spectrum of ethyl cyclobutane carboxylate. 55 100 80 60 40 83 100 20 128 m/z 30 40 50 60 70 80 90 100 110 120 130

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Shown below is the EI mass spectrum of ethyl cyclobutane carboxylate. Without drawing any structures or mechanisms, determine which fragment comes about from a Mclarfetty rearrangement. What jumped out at you? And once you have identifed the fragment ion that comes from the Mclarfetty rearrangement, provide the strcture of the fragment and a clear mechanism for its formation. 

Shown below is the El masS spectrum of ethyl cyclobutane carboxylate.
55
100
80
60
40
83
100
20
128
m/z
30
40
50
60
70
80
90
100
110
120
130
Transcribed Image Text:Shown below is the El masS spectrum of ethyl cyclobutane carboxylate. 55 100 80 60 40 83 100 20 128 m/z 30 40 50 60 70 80 90 100 110 120 130
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