Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Practice Problem 18.14**
Show how you could employ enamines in synthesizing the following compounds:
(a) A cyclohexanone derivative with a six-carbon chain and a ketone group at the end of the chain.
(b) A cyclohexanone derivative with a five-carbon chain and a double bond near the end of the chain.
(c) A cyclic compound with a ketone group and a two-carbon side chain with a ketone group at its terminus.
(d) A naphthalene derivative with an ester group attached to an ethyl chain.
**Explanation of the Structures:**
- **(a)**: The structure consists of a cyclohexanone (a six-membered ring with one ketone group) connected to a six-carbon chain terminating in another ketone group.
- **(b)**: This structure features cyclohexanone with a five-carbon chain, including a double bond between the fourth and fifth carbon.
- **(c)**: This comprises a cyclic compound with a ketone group and an additional two-carbon chain ending with another ketone group.
- **(d)**: The structure represents a naphthalene ring with an ethyl ester group attached.
These exercises focus on applying enamine chemistry to synthesize various organic structures involving cyclohexanone and naphthalene derivatives.
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