Show how you could employ enamines in syntheses of the following compounds:

Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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**Practice Problem 18.14**

Show how you could employ enamines in synthesizing the following compounds:

(a) A cyclohexanone derivative with a six-carbon chain and a ketone group at the end of the chain.

(b) A cyclohexanone derivative with a five-carbon chain and a double bond near the end of the chain.

(c) A cyclic compound with a ketone group and a two-carbon side chain with a ketone group at its terminus.

(d) A naphthalene derivative with an ester group attached to an ethyl chain.

**Explanation of the Structures:**

- **(a)**: The structure consists of a cyclohexanone (a six-membered ring with one ketone group) connected to a six-carbon chain terminating in another ketone group.

- **(b)**: This structure features cyclohexanone with a five-carbon chain, including a double bond between the fourth and fifth carbon.

- **(c)**: This comprises a cyclic compound with a ketone group and an additional two-carbon chain ending with another ketone group.

- **(d)**: The structure represents a naphthalene ring with an ethyl ester group attached.

These exercises focus on applying enamine chemistry to synthesize various organic structures involving cyclohexanone and naphthalene derivatives.
Transcribed Image Text:**Practice Problem 18.14** Show how you could employ enamines in synthesizing the following compounds: (a) A cyclohexanone derivative with a six-carbon chain and a ketone group at the end of the chain. (b) A cyclohexanone derivative with a five-carbon chain and a double bond near the end of the chain. (c) A cyclic compound with a ketone group and a two-carbon side chain with a ketone group at its terminus. (d) A naphthalene derivative with an ester group attached to an ethyl chain. **Explanation of the Structures:** - **(a)**: The structure consists of a cyclohexanone (a six-membered ring with one ketone group) connected to a six-carbon chain terminating in another ketone group. - **(b)**: This structure features cyclohexanone with a five-carbon chain, including a double bond between the fourth and fifth carbon. - **(c)**: This comprises a cyclic compound with a ketone group and an additional two-carbon chain ending with another ketone group. - **(d)**: The structure represents a naphthalene ring with an ethyl ester group attached. These exercises focus on applying enamine chemistry to synthesize various organic structures involving cyclohexanone and naphthalene derivatives.
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