Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:### Reaction Selection Exercise
This image presents a chemistry exercise focused on predicting the outcome of a chemical reaction. The task is to select the final product of a given reaction where an alkyne is treated with hydrogen gas (\( \text{H}_2 \)) in the presence of a Lindlar catalyst.
**Reactant:**
- The compound shown is a terminal alkyne, characterized by a carbon-carbon triple bond and a methyl group attached on one side of the triple bond.
**Reaction Condition:**
- **Reagent/Catalyst:** \( \text{H}_2, \text{Lindlar catalyst} \)
- The Lindlar catalyst is used to partially hydrogenate alkynes to cis-alkenes.
**Options:**
1. **Option 1:** A terminal alkene with a carbon-carbon double bond.
2. **Option 2:** An alkane with single bonds only.
3. **Option 3:** A linear alkene with a double bond in the cis-configuration.
4. **Option 4:** An alkene with a carbon-carbon double bond and a \(\text{Pd}\) (palladium) label, indicating catalyst presence.
**Correct Answer:**
The correct product when an alkyne is hydrogenated using a Lindlar catalyst is a cis-alkene. Therefore, the final product should display a double bond in a cis-configuration as shown in Option 3.
### Explanation of Diagrams:
- **Triple Bond in Reactant:** The triple bond indicates an alkyne, which suggests the importance of achieving selective hydrogenation to form a cis-alkene.
- **Double Bonds in Products:** Each option highlights different possible structures that could theoretically result from the reaction.
This exercise demands understanding of chemical transformations, especially the nuance of partial hydrogenation using specific catalysts.
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