Saturated aldehyde Aromatic aldehyde At what position would you expect to observe IR absorption for the carbonyl groups in the following molecules? Infrared Absorptions of Some Aldehydes and Ketones. Carbonyl type Absorption cm-1 1730 1705 Example CH3CHO PhCHO a,ẞ-Unsaturated H2C=CHCHO 1705 aldehyde Saturated ketone CH3 COCH3 1715 Cyclohexanone 1715 Cyclopentanone 1750 Cyclobutanone Aromatic ketone 1785 PhCOCH3 a,ẞ-Unsaturated ketone H2C=CHCOCH3 1685 1690 Molecule #1: Molecule #2: CHO CHO CH3 cm-1 cm -1

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Saturated aldehyde
Aromatic aldehyde
At what position would you expect to observe IR absorption for the carbonyl
groups in the following molecules?
Infrared Absorptions of Some Aldehydes and Ketones.
Carbonyl type
Absorption
cm-1
1730
1705
Example
CH3CHO
PhCHO
a,ẞ-Unsaturated
H2C=CHCHO
1705
aldehyde
Saturated ketone
CH3 COCH3
1715
Cyclohexanone
1715
Cyclopentanone
1750
Cyclobutanone
Aromatic ketone
1785
PhCOCH3
a,ẞ-Unsaturated ketone H2C=CHCOCH3 1685
1690
Molecule #1:
Molecule #2:
CHO
CHO
CH3
cm-1
cm
-1
Transcribed Image Text:Saturated aldehyde Aromatic aldehyde At what position would you expect to observe IR absorption for the carbonyl groups in the following molecules? Infrared Absorptions of Some Aldehydes and Ketones. Carbonyl type Absorption cm-1 1730 1705 Example CH3CHO PhCHO a,ẞ-Unsaturated H2C=CHCHO 1705 aldehyde Saturated ketone CH3 COCH3 1715 Cyclohexanone 1715 Cyclopentanone 1750 Cyclobutanone Aromatic ketone 1785 PhCOCH3 a,ẞ-Unsaturated ketone H2C=CHCOCH3 1685 1690 Molecule #1: Molecule #2: CHO CHO CH3 cm-1 cm -1
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