Samples of Fe(CO)(PF3)4 show two carbonyl stretching bands, at 2038 and 2009 cm'. a. How is it possible for this compound to exhibit two carbonyl bands? Please draw the possible 16. structures. b. Fe(CO)s has carbonyl bands at 2025 and 2000 cm'. Would you place PF3 above or below CO in the spectrochemical series? Explain briefly.
Samples of Fe(CO)(PF3)4 show two carbonyl stretching bands, at 2038 and 2009 cm'. a. How is it possible for this compound to exhibit two carbonyl bands? Please draw the possible 16. structures. b. Fe(CO)s has carbonyl bands at 2025 and 2000 cm'. Would you place PF3 above or below CO in the spectrochemical series? Explain briefly.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Samples of Fe(CO)(PF3)4 show two carbonyl stretching bands, at 2038 and 2009 cm'.
a. How is it possible for this compound to exhibit two carbonyl bands? Please draw the possible
16.
structures.
b. Fe(CO)s has carbonyl bands at 2025 and 2000 cm"'. Would you place PF3 above or below CO
in the spectrochemical series? Explain briefly.
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