S.No Time (min) СА(mole/L) dCa/dt =ACA/At 1 0.62 0.51 – 0.62 :-0.022 5 - 0 0.42 – 0.51 2 0.51 -0.018 10 – 5 0.36 – 0.42 3 10 0.42 -0.012 15 – 10. 0.31 – 0.36 4 15 0.36 -0.01 20 – 15 20 0.31 LO

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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Question

Find the reaction order (n), reaction rate constant (k) and reaction rate general form using
differential method. ( graphically method)

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S.No
Time (min)
CA (mole/L)
dCA/dt =ACA/At
1
0.62
0.51 – 0.62
-0.022
5-0
0.42 – 0.51
2
5
0.51
-0.018
10 -5
0.36 – 0.42
3
10
0.42
-0.012
15 – 10
0.31 – 0.36
4
15
0.36
-0.01
20 – 15
20
0.31
Transcribed Image Text:S.No Time (min) CA (mole/L) dCA/dt =ACA/At 1 0.62 0.51 – 0.62 -0.022 5-0 0.42 – 0.51 2 5 0.51 -0.018 10 -5 0.36 – 0.42 3 10 0.42 -0.012 15 – 10 0.31 – 0.36 4 15 0.36 -0.01 20 – 15 20 0.31
Zeroth Order
First Order
Second Order
Differential
ALA] = K(A)
A[A] = K(AJ?
ΔΙΑ
Rate
= k
At
Rate =-
At
rate law
Rate
At
Concentration
vs. time
Time
Time
Time
Concentration
Concentration
Concentration
Transcribed Image Text:Zeroth Order First Order Second Order Differential ALA] = K(A) A[A] = K(AJ? ΔΙΑ Rate = k At Rate =- At rate law Rate At Concentration vs. time Time Time Time Concentration Concentration Concentration
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