s the function w(x)= sinx an eigenfunction for the linear momentum pperator, 6,? ? If yes, what is the eigenvalue? O Yes, the eigenvalue is -1 O Yes, the eigenvalue is sinx Yes, the eigenvalue is – iħ No
s the function w(x)= sinx an eigenfunction for the linear momentum pperator, 6,? ? If yes, what is the eigenvalue? O Yes, the eigenvalue is -1 O Yes, the eigenvalue is sinx Yes, the eigenvalue is – iħ No
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:Observable
Operator
Classical counterpart
Position
x = x:
And so forth for coordinates
other than x
Momentum (linear)
Px = mvx
Px = -ih-
And so forth for coordinates
other than x
Momentum (angular)
Lx = yP: - zPy
I, = - ih ŷ
az
mi -
K = =mv;
Kinetic energy, 1-D
%3D
K =
2m dx
2m
Kinetic energy, 3-D
+ v, + v)
%3D
+
2m ax
dy az,
pi + p; + p?
2m
Potential energy:
Harmonic oscillator
kx².
V = -kx
%3D
Coulombic
91 92
91 92
V =
%3D
4TEor
h? ( a?
ay
Total energy
+ V H=
2m
P + V
2m ax
az

Transcribed Image Text:Is the function w(x) = sinx an eigenfunction for the linear momentum
operator, 6.? If yes, what is the eigenvalue?
O Yes, the eigenvalue is -1
Yes, the eigenvalue is sinx
O Yes, the eigenvalue is – in
O No
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