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- (ii) Draw the product R, including a detailed reaction mechanism for the conjugate addition reaction between the 1,3-dicarbonyl P and the a,ß-unsaturated ketone Q. Eto P OEt + Q OEt Et3N R (iv) Explain why conjugate addition is favoured over direct addition to Q in this case.For each IUPAC name, draw the complete structure. (a) (25,3R.4R)-2,3-diamino-4-hydroxycyclopentanone; (b) (2R.3R)-2-butyl-3-hydroxypentanedial: (c) (4S,5R)-4.5-diaminoheptane-2,3,6-trione: (d) (3E,5R,6Z)-5-hydroxy-7-methoxyocta-3,6-dien-2-oneWhich stereoisomer of 3-hexene forms (3S,4S)-4-bromo-3-hexanol and (3R,4R)-4-bromo-3-hexanol when it reacts with Br2 and H2O?
- (a) Provide the missing reagents and line structures of the products (C- E) for the following reactions. Include stereochemistry for products Cand E as indicated. No mechanisms are required. (5) C H,0 Show stereochemistry any one diastereomer OH PCC. CH;Cla D H. Pd/C Show stereochemistry any one enantlomerWhat is the appropriate systematic name for the compound below? HO., SH ) (15,45)-4-hydroxycyclohex-2-enethiol O (35,65)-6-mercaptocyclohexen-3-ol )(1S,4S)-4-mercaptocyclohex-2-enol (3S,65)-6-hydroxycyclohexene-3-thiolWhat organic product is formed when 1‑methylcyclopentene is treated with NMMO in the presence of H2O and a catalytic amound of OsO4? Clearly show stereochemistry by drawing a wedge and dashed bond for each chiral carbon. Only draw one stereoisomer if more than one can be formed.
- a Give the chemical structure of (2R.3S)-2,3-dibromopentane b. Identify the following pairs of compounds as either enantiomers, diastercomers, or identical CN .COOH он CCH но CCH and NC COOH Give the structure of any reagent that can be used to enantiomerically resolve R- and S- ibuprofenDraw the organic products formed when cyclopentene is treated withfollowing reagent. [1] OsO4 + NMO; [2] NaHSO3, H2OH3C₂ Br H₂O a. Enantiopure (1R, 3R)-3-Methylcyclohexanol b. Achiral 1-Methylcyclohexanol C. Racemic mixture (1R, 3R)- and (1S, 3S)-3-Methylcyclohexanol d. Diastereomeric mixture of (1R, 3R)- and (1S, 3R)-3-Methycyclohexanol
- 7:21 PM Thu Jul 7 2req 2req ts 2req pts 2req 1 pts 2req [Review Topics] Provide an IUPAC name for the structure shown. ball & stick-labels (Do not use stereochemical terms in you name.) Submit Answer Retry Entire Group 9 more group attempts remaining [References] 29%Chemistry 60. Give the principal product(s) expected, if any, when trans-1,3-pentadiene reacts under the following conditions. Assume one equivalent of each reagent reacts unless noted otherwise. (a) H2O, H3O+ (b) Na+EtO- in EtOH (c) Maleic anhydride heat79 3. Complete the following reaction and write a mechanism for both the substitution and elimination products (both substitution and elimination products occur simultaneously). Discuss all criteria including stereochemistry when a chiral secondary primary alkyl halide with (S) configuration reacts with methanol a weak nucleophile. Draw energy profile for this reaction. (4 points) CH2CH3 CH₂O-Na+ + Br H3C (S) no 1999b 02.907 90 +20110