Ruthenocene, [Ru(h5-C5H5)2], is a relatively stable compound that can be handled and stored at room temperature.1 In contrast, rhodocene, [Rh(h5-C5H5)2], is only stable under "extreme" conditions (e.g. £ -196 °C). At room temperature, rhodocene dimerises to give a species with formula [Rh(C5H5)2]2.2

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Chapter1: Chemical Foundations
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Ruthenocene, [Ru(h5-C5H5)2], is a relatively
stable compound that can be handled and
stored at room temperature.1 In contrast,
rhodocene, [Rh(h5-C5H5)2], is only stable
under "extreme" conditions (e.g. £ -196 °C). At
room temperature, rhodocene dimerises to
give a species with formula [Rh(C5H5)2]2.2
(a) Draw chemical structures for [Ru(h5-
C5H5)2], [Rh(h5-C5H5)2] and [Rh(C5H5)2]2.
(b) For [Ru(h5-C5H5)2] and [Rh(h5-C5H5)2],
draw the frontier molecular orbital diagrams.
(c) Explain the different chemical properties
observed for ruthenocene and rhodocene at
room temperature.
Transcribed Image Text:Ruthenocene, [Ru(h5-C5H5)2], is a relatively stable compound that can be handled and stored at room temperature.1 In contrast, rhodocene, [Rh(h5-C5H5)2], is only stable under "extreme" conditions (e.g. £ -196 °C). At room temperature, rhodocene dimerises to give a species with formula [Rh(C5H5)2]2.2 (a) Draw chemical structures for [Ru(h5- C5H5)2], [Rh(h5-C5H5)2] and [Rh(C5H5)2]2. (b) For [Ru(h5-C5H5)2] and [Rh(h5-C5H5)2], draw the frontier molecular orbital diagrams. (c) Explain the different chemical properties observed for ruthenocene and rhodocene at room temperature.
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