References Submit Answer Use the References to access important values if needed for this question. Determine the pH change when 0.102 mol KOH is added to 1.00 L of a buffer solution that is 0.372 M in HCIO and 0.373 M in CIO™. pH after addition - pH before addition pH before addition = pH change =

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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**Educational Content: Buffer Solution pH Change Analysis**

---

**Objective:**
Learn how to determine the pH change when a base is added to a buffer solution.

**Problem Statement:**
Determine the pH change when 0.102 mol KOH is added to 1.00 L of a buffer solution that is 0.372 M in HClO and 0.373 M in ClO⁻.

**Procedure:**
1. **Calculate the pH before the addition of KOH.**
   - Use the Henderson-Hasselbalch equation: 
     \[
     \text{pH} = \text{pKa} + \log \left(\frac{[\text{Base}]}{[\text{Acid}]}\right)
     \]
   - Identify pKa for HClO.
   - Plug in concentrations: [Base] = 0.373 M, [Acid] = 0.372 M.

2. **Calculate the pH after the addition of KOH.**
   - The added KOH reacts fully with the weak acid, HClO.
   - Adjust concentrations based on the reaction:
     \[
     \begin{align*}
     \text{New } [\text{Acid}] &= [\text{HClO}] - 0.102 \, \text{mol/L}, \\
     \text{New } [\text{Base}] &= [\text{ClO}^{-}] + 0.102 \, \text{mol/L}.
     \end{align*}
     \]
   - Calculate new pH using the Henderson-Hasselbalch equation.

3. **Determine the pH change.**
   - Subtract the initial pH from the pH after addition.

**Interactive Elements:**
- Input boxes for calculating initial and final pH.
- A "Submit Answer" button to verify calculations.

**Notes:**
- This lesson applies the Henderson-Hasselbalch equation to assess buffer capacity.
- It is a group attempt with automated saving features, ensuring progress is not lost.
- Engage with the problem consecutively through varied attempts to deepen understanding.

**Technical Features:**
- Autosaved progress at time stamps.
- Encourages collaborative problem-solving skills.
Transcribed Image Text:**Educational Content: Buffer Solution pH Change Analysis** --- **Objective:** Learn how to determine the pH change when a base is added to a buffer solution. **Problem Statement:** Determine the pH change when 0.102 mol KOH is added to 1.00 L of a buffer solution that is 0.372 M in HClO and 0.373 M in ClO⁻. **Procedure:** 1. **Calculate the pH before the addition of KOH.** - Use the Henderson-Hasselbalch equation: \[ \text{pH} = \text{pKa} + \log \left(\frac{[\text{Base}]}{[\text{Acid}]}\right) \] - Identify pKa for HClO. - Plug in concentrations: [Base] = 0.373 M, [Acid] = 0.372 M. 2. **Calculate the pH after the addition of KOH.** - The added KOH reacts fully with the weak acid, HClO. - Adjust concentrations based on the reaction: \[ \begin{align*} \text{New } [\text{Acid}] &= [\text{HClO}] - 0.102 \, \text{mol/L}, \\ \text{New } [\text{Base}] &= [\text{ClO}^{-}] + 0.102 \, \text{mol/L}. \end{align*} \] - Calculate new pH using the Henderson-Hasselbalch equation. 3. **Determine the pH change.** - Subtract the initial pH from the pH after addition. **Interactive Elements:** - Input boxes for calculating initial and final pH. - A "Submit Answer" button to verify calculations. **Notes:** - This lesson applies the Henderson-Hasselbalch equation to assess buffer capacity. - It is a group attempt with automated saving features, ensuring progress is not lost. - Engage with the problem consecutively through varied attempts to deepen understanding. **Technical Features:** - Autosaved progress at time stamps. - Encourages collaborative problem-solving skills.
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