References Submit Answer Use the References to access important values if needed for this question. Determine the pH change when 0.102 mol KOH is added to 1.00 L of a buffer solution that is 0.372 M in HCIO and 0.373 M in CIO™. pH after addition - pH before addition pH before addition = pH change =
References Submit Answer Use the References to access important values if needed for this question. Determine the pH change when 0.102 mol KOH is added to 1.00 L of a buffer solution that is 0.372 M in HCIO and 0.373 M in CIO™. pH after addition - pH before addition pH before addition = pH change =
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Educational Content: Buffer Solution pH Change Analysis**
---
**Objective:**
Learn how to determine the pH change when a base is added to a buffer solution.
**Problem Statement:**
Determine the pH change when 0.102 mol KOH is added to 1.00 L of a buffer solution that is 0.372 M in HClO and 0.373 M in ClO⁻.
**Procedure:**
1. **Calculate the pH before the addition of KOH.**
- Use the Henderson-Hasselbalch equation:
\[
\text{pH} = \text{pKa} + \log \left(\frac{[\text{Base}]}{[\text{Acid}]}\right)
\]
- Identify pKa for HClO.
- Plug in concentrations: [Base] = 0.373 M, [Acid] = 0.372 M.
2. **Calculate the pH after the addition of KOH.**
- The added KOH reacts fully with the weak acid, HClO.
- Adjust concentrations based on the reaction:
\[
\begin{align*}
\text{New } [\text{Acid}] &= [\text{HClO}] - 0.102 \, \text{mol/L}, \\
\text{New } [\text{Base}] &= [\text{ClO}^{-}] + 0.102 \, \text{mol/L}.
\end{align*}
\]
- Calculate new pH using the Henderson-Hasselbalch equation.
3. **Determine the pH change.**
- Subtract the initial pH from the pH after addition.
**Interactive Elements:**
- Input boxes for calculating initial and final pH.
- A "Submit Answer" button to verify calculations.
**Notes:**
- This lesson applies the Henderson-Hasselbalch equation to assess buffer capacity.
- It is a group attempt with automated saving features, ensuring progress is not lost.
- Engage with the problem consecutively through varied attempts to deepen understanding.
**Technical Features:**
- Autosaved progress at time stamps.
- Encourages collaborative problem-solving skills.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F47386969-f92b-4827-b6d7-02bdac2aa892%2F0203fcd6-2352-40d5-9735-b22e279cf708%2Fbr0cuoa_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Educational Content: Buffer Solution pH Change Analysis**
---
**Objective:**
Learn how to determine the pH change when a base is added to a buffer solution.
**Problem Statement:**
Determine the pH change when 0.102 mol KOH is added to 1.00 L of a buffer solution that is 0.372 M in HClO and 0.373 M in ClO⁻.
**Procedure:**
1. **Calculate the pH before the addition of KOH.**
- Use the Henderson-Hasselbalch equation:
\[
\text{pH} = \text{pKa} + \log \left(\frac{[\text{Base}]}{[\text{Acid}]}\right)
\]
- Identify pKa for HClO.
- Plug in concentrations: [Base] = 0.373 M, [Acid] = 0.372 M.
2. **Calculate the pH after the addition of KOH.**
- The added KOH reacts fully with the weak acid, HClO.
- Adjust concentrations based on the reaction:
\[
\begin{align*}
\text{New } [\text{Acid}] &= [\text{HClO}] - 0.102 \, \text{mol/L}, \\
\text{New } [\text{Base}] &= [\text{ClO}^{-}] + 0.102 \, \text{mol/L}.
\end{align*}
\]
- Calculate new pH using the Henderson-Hasselbalch equation.
3. **Determine the pH change.**
- Subtract the initial pH from the pH after addition.
**Interactive Elements:**
- Input boxes for calculating initial and final pH.
- A "Submit Answer" button to verify calculations.
**Notes:**
- This lesson applies the Henderson-Hasselbalch equation to assess buffer capacity.
- It is a group attempt with automated saving features, ensuring progress is not lost.
- Engage with the problem consecutively through varied attempts to deepen understanding.
**Technical Features:**
- Autosaved progress at time stamps.
- Encourages collaborative problem-solving skills.
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