[Referen Calculate the standard free-energy change at 25°C for the following reaction: 4Cr(s) + 302 (9) + 12H* (aq) + 4Cr** (aq) + 6H;O(1) Use standard electrode potentials. Standard Electrode (Reduction) Potentials in Aqueous Solution at 25C Standard Cathode (Reduction) Half-Reaction Potential, E (V) Lit (ag) +e Li(s) -3.04 Na* (ag) +e Na(8) Mg+ (aq) +2e Mg(s) 1, -2.71 -2.38 Al (aq) +3e Al(s) -1.66 2H20(1) + 2e H2 (g) + 20H (aq) Zn+ (ag) + 2e Zn(s) -0.83 -0.76 Crt (ag) +3e Cr(s) --0.74 Fe?+ (aq) + 2e Fe(s) -0.41 Cd²+ (ag) + 2e Cd(s) -0.40 Ni+ (ag) + 2e Ni(s) --0.23 Sn+ (ag) + 2e Sn(s) -0.14 Pb+ (ag) + 2e Pb(s) -0.13 Fet (aq)+3e Fe(s) -0.04 2H (ag) + 2e H2(9) 0.00 Sn (ag) + 2e Sn+ (aq) 0.15 Cu* (ag) +e Cu* (aq) 0.16 Cu+ (aq) + 2e Cu(s) 0.34 IO (aq) + H2O(1) + 2e I(aq) + 20H (aq) 0.49 Cu (aq) +e Cu(s) 0.52 L (s) +2e 21 (aq) 0.54 D.3+

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193r.) 

2H (ag) +2e –H (g)
0.00
Snt (ag) + 2e= Sn²+ (aq)
0.15
Cu+ (ag) + e= Cu* (aq)
0.16
Cu+ (ag) + 2e Cu(s)
0.34
IO (ag) + H2 O(1) + 2e I (aq) + 20H (aq)
0.49
Cu" (ag) + e Cu(s)
0.52
2(s) + 2e = 21 (aq)
0.54
Fe (aq) +e Fe+ (aq)
0.77
Hg, (aq) + 2e 2Hg(1)
0.80
Ag" (ag) +e Ag(s)
0.80
Hg (ag) + 2e Hg(1)
0.85
CIO (ag) + H2 0(1) + 2e Cl (ag) + 20H (aq)
0.90
2H3²+ (ag) + 2e - Hg,+ (aq)
0.90
NO: (ag) + 4H (aq) + 3e NO(g) +2H2 O(1)
0.96
Br2 (1) + 2e 2Br (ag)
1.07
O2 (g) + 4H (ag) + 4e 2H,0(1)
1.23
Cr2 0,2 (ag) + 14H (ag) + 6e 2Cr (aq) + 7H20(1) 1.33
Cl. (g) + 2e = 2C1 (ag)
1.36
MnO4 (ag) + 8H (aq) + 5e Mn (aq) + 4H2 O(1)
2+
1.49
H2O2(aq) + 2H* (aq) + 2e 2H2 O(1)
1.78
S,03 (ag) + 2e = 2S0,2 (ag)
2.01
F2(g) + 2e 2F (ag)
2.87
Standard free-energy change
kJ
Transcribed Image Text:2H (ag) +2e –H (g) 0.00 Snt (ag) + 2e= Sn²+ (aq) 0.15 Cu+ (ag) + e= Cu* (aq) 0.16 Cu+ (ag) + 2e Cu(s) 0.34 IO (ag) + H2 O(1) + 2e I (aq) + 20H (aq) 0.49 Cu" (ag) + e Cu(s) 0.52 2(s) + 2e = 21 (aq) 0.54 Fe (aq) +e Fe+ (aq) 0.77 Hg, (aq) + 2e 2Hg(1) 0.80 Ag" (ag) +e Ag(s) 0.80 Hg (ag) + 2e Hg(1) 0.85 CIO (ag) + H2 0(1) + 2e Cl (ag) + 20H (aq) 0.90 2H3²+ (ag) + 2e - Hg,+ (aq) 0.90 NO: (ag) + 4H (aq) + 3e NO(g) +2H2 O(1) 0.96 Br2 (1) + 2e 2Br (ag) 1.07 O2 (g) + 4H (ag) + 4e 2H,0(1) 1.23 Cr2 0,2 (ag) + 14H (ag) + 6e 2Cr (aq) + 7H20(1) 1.33 Cl. (g) + 2e = 2C1 (ag) 1.36 MnO4 (ag) + 8H (aq) + 5e Mn (aq) + 4H2 O(1) 2+ 1.49 H2O2(aq) + 2H* (aq) + 2e 2H2 O(1) 1.78 S,03 (ag) + 2e = 2S0,2 (ag) 2.01 F2(g) + 2e 2F (ag) 2.87 Standard free-energy change kJ
[Referenc
Calculate the standard free-energy change at 25°C for the following reaction:
4Cr(s) + 302 (g) + 12H*(ag) → 4Cr (ag) +6H,O(1)
Use standard electrode potentials.
Standard Electrode (Reduction) Potentials in Aqueous Solution at 25°C
Cathode (Reduction)
Standard
Half-Reaction
Potential, E (V)
Lit (ag) +e=Li(s)
Na* (aq) +e Na(s)
-3.04
-2.71
Mg+ (ag) + 2e - Mg(s)
-2.38
Al+ (ag) + 3e - Al(s)
-1,66
2H20(1) + 2e - H (g) + 20H (ag)
-0.83
Zn (ag) + 2e - Zn(s)
-0.76
Cr+ (ag) + 3e Cr(s)
-0.74
Fe?+ (aq) + 2e - Fe(s)
-0.41
Cd²+ (ag) + 2e - Cd(s)
-0.40
Ni?+ (ag) + 2e - Ni(s)
-0.23
Sn²+ (ag) + 2e Sn(s)
-0.14
Pb (ag) + 2e Pb(s)
-0.13
Fet (ag) +3e Fe(s)
-0,04
2H (ag) + 2e H2 (g)
0.00
Sn (ag) +2e S (aq)
2+
0.15
Cu²+ (aq) + e Cu* (aq)
0.16
Cu?+ (ag) + 2e - Cu(s)
0.34
IO (ag) + H2O(1) + 2e I(ag) + 20H (ag)
0.49
Cu* (ag) +e Cu(s)
0.52
L(s) + 2e 21 (ag)
0.54
A77
Cengage Learning ( Cengage Technical Support
Transcribed Image Text:[Referenc Calculate the standard free-energy change at 25°C for the following reaction: 4Cr(s) + 302 (g) + 12H*(ag) → 4Cr (ag) +6H,O(1) Use standard electrode potentials. Standard Electrode (Reduction) Potentials in Aqueous Solution at 25°C Cathode (Reduction) Standard Half-Reaction Potential, E (V) Lit (ag) +e=Li(s) Na* (aq) +e Na(s) -3.04 -2.71 Mg+ (ag) + 2e - Mg(s) -2.38 Al+ (ag) + 3e - Al(s) -1,66 2H20(1) + 2e - H (g) + 20H (ag) -0.83 Zn (ag) + 2e - Zn(s) -0.76 Cr+ (ag) + 3e Cr(s) -0.74 Fe?+ (aq) + 2e - Fe(s) -0.41 Cd²+ (ag) + 2e - Cd(s) -0.40 Ni?+ (ag) + 2e - Ni(s) -0.23 Sn²+ (ag) + 2e Sn(s) -0.14 Pb (ag) + 2e Pb(s) -0.13 Fet (ag) +3e Fe(s) -0,04 2H (ag) + 2e H2 (g) 0.00 Sn (ag) +2e S (aq) 2+ 0.15 Cu²+ (aq) + e Cu* (aq) 0.16 Cu?+ (ag) + 2e - Cu(s) 0.34 IO (ag) + H2O(1) + 2e I(ag) + 20H (ag) 0.49 Cu* (ag) +e Cu(s) 0.52 L(s) + 2e 21 (ag) 0.54 A77 Cengage Learning ( Cengage Technical Support
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