Reagents. Provide reagents for the following transformations, A - H. In some cases, there are multiple correct answers. If there are two steps indicate this with a 1.), 2.), etc. [Pay close attention to the direction of the arrows!] H SH A C HO B OH HS A: B: C: D: Br OH E: F: `G: H: OH OH G
Reactive Intermediates
In chemistry, reactive intermediates are termed as short-lived, highly reactive atoms with high energy. They rapidly transform into stable particles during a chemical reaction. In specific cases, by means of matrix isolation and at low-temperature reactive intermediates can be isolated.
Hydride Shift
A hydride shift is a rearrangement of a hydrogen atom in a carbocation that occurs to make the molecule more stable. In organic chemistry, rearrangement of the carbocation is very easily seen. This rearrangement can be because of the movement of a carbocation to attain stability in the compound. Such structural reorganization movement is called a shift within molecules. After the shifting of carbocation over the different carbon then they form structural isomers of the previous existing molecule.
Vinylic Carbocation
A carbocation where the positive charge is on the alkene carbon is known as the vinyl carbocation or vinyl cation. The empirical formula for vinyl cation is C2H3+. In the vinyl carbocation, the positive charge is on the carbon atom with the double bond therefore it is sp hybridized. It is known to be a part of various reactions, for example, electrophilic addition of alkynes and solvolysis as well. It plays the role of a reactive intermediate in these reactions.
Cycloheptatrienyl Cation
It is an aromatic carbocation having a general formula, [C7 H7]+. It is also known as the aromatic tropylium ion. Its name is derived from the molecule tropine, which is a seven membered carbon atom ring. Cycloheptatriene or tropylidene was first synthesized from tropine.
Stability of Vinyl Carbocation
Carbocations are positively charged carbon atoms. It is also known as a carbonium ion.
![Reagents. Provide reagents for the following transformations, A - H. In some cases, there are multiple correct answers.
If there are two steps indicate this with a 1.), 2.), etc. [Pay close attention to the direction of the arrows!]
H
SH
HO
G
В
OH
E
HS
Br
ОН
OH
ОН
A:
E:
В:
F:
С:
`G:
D:
H:](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fc0cd64b3-d22c-4f80-aac4-ddd0e7174ead%2Fbec87b38-73f7-4a14-8484-5761c21d2d0e%2Fej4rdi5_processed.png&w=3840&q=75)
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